High solids coating composition of an acrylic polymer a polyester polyol and an alkylated melamine crosslinking agent
AssigneeE. I. Du Pont de Nemours and Company
InventorPaul L. Adesko
Life of this patent
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Abstract
The high solids coating composition contains at least 40% by weight of a binder of film-forming constituents in which the constituents are of (1) an acrylic polymer of styrene or methyl methacrylate or mixtures thereof, an alkyl acrylate or an alkyl methacrylate and a hydroxyl alkyl acrylate or methacrylate (2) a polyester polyol and (3) an alkylated melamine formaldehyde crosslinking agent and optionally, an acid catalyst; the composition is particularly useful as a primer or an exterior finish for automobiles, trucks, airplanes and can be used as an appliance finish and for coil coatings.
Claims13
A high solids coating composition comprising at least 40% by weight of a binder of film-forming constituents and up to 60% by weight of a nonaqueous liquid carrier;
- in which the film-forming constituents consist essentially of about
- (1) 10-50% by weight, based on the weight of the binder, of an acrylic polymer consisting essentially of
- (a) 10-50% by weight, based on the weight of the polymer, of styrene, methylmethacrylate or mixtures thereof;
- (b) 30-70% by weight, based on the weight of the polymer, of an alkyl methacrylate, or an alkyl acrylate each having 2-12 carbon atoms in the alkyl group, and
- (c) 15-50% by weight, based on the weight of the polymer, of a hydroxyl alkyl acrylate or methacrylate having 2-4 carbon atoms in the alkyl group;
- and
- the polymer having a number average molecular weight of 500-20,000;
- (2) 10-60% by weight, based on the weight of the binder, of a polyester polyol having a number average molecular weight of 1500 or less and an acid number of 20 or less which is the reaction product of
- (a) neopentyl glycol and at least one other hindered diol containing two methylol groups wherein each methylol group is attached directly to a cycloaliphatic or aromatic structure or to a tertiary carbon atom, the molar ratio of neopentyl glycol to hindered diol being 2:1 to 6:1, and
- (b) a mixture of aromatic and aliphatic dicarboxylic acids wherein the molar ratio of aromatic acid to aliphatic acid is from 1.5:1 to 10:1,
- wherein the molar ratio of (a) to (b) is from 1.3:1 to 1.9:1 and wherein the polyol has a hydroxy content of about 3.0-10.0% by weight;
- (3) 15-40% by weight, based on the weight of the binder, of a fully or partially alkylated melamine formaldehyde crosslinking agent having 1-4 carbon atoms in the alkyl group.
Dependencies are inferred from the claim text.