Aqueous dispersions of polyvinylbutyral having low content of hydrosolubles
AssigneeRhone-Poulenc Industries
InventorJean-Marie Pouchol
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Abstract
Aqueous dispersions of particulate polyvinylbutyral are disclosed, said dispersions comprising an amount of hydrosolubles dissolved in the aqueous phase thereof, the content in the dispersions of said dissolved hydrosolubles being less than about 2.5% by weight, based upon the weight of the polyvinylbutyral. Said dispersions are useful in the formulation of certain coating compositions, e.g., paints and varnishes.
Claims10
A process for preparing an aqueous dispersion of polyvinylbutyral having a particle size of from about 0.01.mu. to 5.mu. and containing, dissolved therein, less than about 2.5% by weight of hydrosoluble compounds relative to the weight of polyvinylbutyral, comprising the steps of
- (a) bringing an aqueous dispersion of the polyvinylbutyral, formed by reacting polyvinyl alcohol with butyraldehyde in an aqueous medium, in an aqueous solution containing, dissolved therein, an amount of no more than 2.5% by weight of hydrosoluble compounds relative to the weight of polyvinylbutyral, into contact with a semipermeable ultrafiltration membrane in such a manner that a portion of the aqueous dispersion comprising the polyvinylbutyral particles is retained and a sufficient portion of the aqueous solution is filtrated through the membrane in order to remove such an amount of hydrosoluble compounds that the amount of hydrosoluble compounds within the retained portion of the dispersion is reduced to less than about 2.5% by weight relative to the weight of the polyvinylbutyral and
- (b) in the course of the ultrafiltration, adding to the retained portion of the dispersion a sufficient amount of deionized water in order to replace at least a major part of the filtrated off portion of the aqueous solution.
Dependencies are inferred from the claim text.