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US 4,396,736 AGranted
Flame-proofed polyamide moulding materials
AssigneeBayer Aktiengesellschaft
InventorsRolf Dhein, Ludwig Rottmaier, Rudolf Merten, Wolfgang Siebourg
Life of this patent
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Abstract
Polyamide moulding compositions containing triazolidine-3,5-diones or reaction products thereof as flame retarding agents.
Claims4
A self-extinguishing, optionally reinforced thermoplastic polyamide molding composition containing alkyl as a flame-proofing agent from 0.1 to 20% by weight of a compound selected from the group consisting of ##STR12## wherein R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.4 -C.sub.6 cycloalkyl or phenyl substituted by CH.sub.3,
- R.sup.3 is a C.sub.1 -C.sub.6 aliphatic, C.sub.4 -C.sub.10 cycloaliphatic or a CH.sub.3 -substituted C.sub.6 -C.sub.12 aromatic radical and
- a is an integer from 2 to 5;
- ##STR13## wherein R.sup.5 individually is hydrogen;
- a C.sub.1 -C.sub.10 aliphatic radical;
- a C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical;
- or one of said radicals substituted by halogen, hydroxy or C.sub.1 -C.sub.4 alkoxy;
- R.sup.6 individually is a C.sub.1 -C.sub.10 aliphatic radical;
- a C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical;
- or one of said radicals substituted by halogen, cyano, hydroxy, amino, C.sub.1 -C.sub.4 alkylamino, C.sub.1 -C.sub.4 dialkylamino, C.sub.1 -C.sub.4 alkoxy, ##STR14## hydroxycarbonyl or C.sub.2 -C.sub.4 alkoxycarbonyl;
- R.sup.5 and R.sup.6 taken together with the nitrogen atom to which each are joined form a cyclic C.sub.2 -C.sub.8 heterocyclic radical;
- R.sup.7 is hydrogen;
- a C.sub.1 -C.sub.6 aliphatic radical;
- a C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical or one of said radicals substituted by halogen or hydroxy and x is 0 to 2;
- ##STR15## wherein R.sup.3 ' is hydrogen, a C.sub.1 -C.sub.20 aliphatic radical, a C.sub.4 -C.sub.17 cycloaliphatic radical, a C.sub.7 -C.sub.17 araliphatic radical, or a C.sub.6 -C.sub.15 aromatic radical;
- R.sup.5 and R.sup.6 are as defined above in (B);
- a' is a integer of from 1 to 5;
- b is an integer of from 1 to 2a' and
- c is an integer of from 2a'-b and ##STR16## wherein R.sup.9 is hydrogen;
- a C.sub.2 -C.sub.10 alkylcarbonyl radical;
- a C.sub.1 -C.sub.10 aliphatic radical;
- C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical or one of said radicals substituted by halogen or hydroxy;
- R.sup.10 is a hydrogen;
- a C.sub.1 -C.sub.10 aliphatic radical;
- a C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical;
- or one of said radicals substituted by halogen;
- hydroxy or C.sub.1 -C.sub.4 alkoxy;
- or a radical of the formula ##STR17## wherein R.sup.9 is as aforesaid;
- R.sup.11 is a C.sub.1 -C.sub.10 aliphatic radical;
- a C.sub.4 -C.sub.10 cycloaliphatic radical;
- a C.sub.7 -C.sub.10 araliphatic radical;
- a C.sub.6 -C.sub.10 aromatic radical;
- one of said radicals substituted by halogen, cyano, hydroxy, amino, C.sub.1 -C.sub.10 alkylamino, C.sub.1 -C.sub.10 dialkylamino, C.sub.1 -C.sub.10 alkoxy ##STR18## hydroxycarbonyl or C.sub.2 -C.sub.10 alkoxycarbonyl;
- a carbonyl group;
- a group of the formula ##STR19## wherein R.sup.4 is a bond;
- hydrogen;
- an amino group;
- a C.sub.1 -C.sub.20 aliphatic radical;
- a C.sub.4 -C.sub.17 cycloaliphatic radical;
- a C.sub.7 -C.sub.17 araliphatic radical;
- a C.sub.6 -C.sub.15 aromatic radical or one of said radicals substituted by halogen.
47 more elements
Dependencies are inferred from the claim text.