US 4,396,531 AGranted

Fluid catalyst regeneration process and apparatus

AssigneeUop LLC

InventorDavid A. Lomas

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Abstract

A catalyst regeneration process and apparatus for the oxidative removal of coke from a coke contaminated fluid catalyst for use of the catalyst in a catalytic cracking reaction zone. The process comprises a high temperature coke combustion zone, a catalyst disengagement zone and an external heat removal zone comprising a shell and tube heat exchanger. A mixture of coke contaminated catalyst, and oxygen containing gas are contacted in the high temperature combustion zone. Catalyst is cooled by passing it through the shell side of the heat exchanger with a cooling medium through the tube side. The cooled catalyst is passed to the reaction zone. The catalyst is maintained in the cooling zone as a dense phase fluidized bed by passing a fluidizing gas into the bottom of the shell side. Steam is the preferred fluidizing gas. The rate at which fluidizing gas is passed to the bottom portion of the shell of the heat exchanger is adjusted to optimize the quantity of heat transferred to the cooling medium in the tubes, the passivation of contaminating metals on the catalyst and the stripping of inerts from the catalyst.

A process for regenerating a coke contaminated fluid catalyst for use in a fluidized catalytic cracking reaction zone, said process including the steps of:

(a) introducing oxygen containing regeneration gas and coke contaminated fluid catalyst into a lower locus of a combustion zone maintained at a temperature sufficient for coke oxidation and therein oxidizing coke to produce hot regenerated catalyst and hot flue gas;
(b) transporting said hot flue gas and said hot regenerated catalyst from an upper locus of said combustion zone into a regenerated catalyst disengaging zone, wherein said hot regenerated catalyst is separated from said flue gas;
(c) transporting said hot regenerated catalyst from said disengaging zone to the upper locus of a cooling zone separate and extrinsic from said disengaging zone where in said cooling zone said hot regenerated catalyst is passed downwardly in indirect heat exchange with an aqueous cooling fluid enclosed in a heat exchange means inserted into said cooling zone to produce relatively cool regenerated catalyst, said catalyst being maintained in said cooling zone as a dense phase fluidized bed by passing a fluidizing gas comprising steam upwardly through such bed, wherein the rate of flow of said stream to said cooling zone is adjusted to achieve optimization of a combination of variables comprising:
(i) the quantity of heat to be withdrawn from said catalyst in said cooling zone;
(ii) the extent of passivation of contaminating metals comprising nickel and vanadium desired by the passage of said steam, or
(iii) the extent of stripping of non-condensible gases from said catalyst being cooled in said separate and extrinsic cooling zone;
and
(d) withdrawing said relatively cool regenerated catalyst from a lower locus of said cooling zone and transporting said catalyst to said fluidized catalytic cracking reaction zone and passing said fluidizing gas comprising steam from said cooling zone into the catalyst in said disengaging zone.

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Abstract

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