Process for reducing ramsbottom carbon test of asphalt
AssigneeShell Oil Company
InventorsJacobus Eilers, Willem H. J. Stork
Life of this patent
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Abstract
In the preparation of a heavy oil with a low Ramsbottom Carbon Test (RCT) from a precipitation asphalt by a two-stage process comprising catalytic hydrotreatment followed by solvent deasphalting and recycle of the separated asphalt to the first stage, the catalytic hydrotreatment for RCT reduction in the first stage is carried out at such severity that the C.sub.4.sup.- gas production per percent RCT reduction is kept between defined limits.
Claims10
A process for the preparation of a hydrocarbon mixture having an RCT of (a) %w and an initial boiling point of T.sub.1 .degree.C., wherein a mixture of an asphaltic bitumen I obtained in the solvent deasphalting of a distillation residue from a crude mineral oil, which asphaltic bitumen I has an RCT of (b) %w and an average molecular weight M, and an asphaltic bitumen II separated in the solvent deasphalting of a residue obtained in the distillation of a hydrotreated residual fraction of a crude mineral oil, which asphaltic bitumen II has an RCT of (c) %w, which mixture comprises less than 50 pbw of asphaltic bitumen II per 100 pbw of asphaltic bitumen I, is subjected to a catalytic hydrotreatment with the object of reducing the RCT;
- the product obtained is separated by distillation into an atmospheric distillate and an atmospheric residue having an initial boiling point of T.sub.1 .degree.C.;
- either from the atmospheric residue so much asphaltic bitumen is separated by solvent deasphalting that a deasphalted atmospheric residue having the desired RCT of (a) %w is obtained, or the atmospheric residue is separated by distillation into a vacuum distillate and a vacuum residue, from which vacuum residue so much asphaltic bitumen is separated by solvent deasphalting that a deasphalted vacuum residue is obtained having an RCT which is such that, when this deasphalted vacuum residue is mixed with the vacuum distillate, a mixture is obtained which has the desired RCT of (a) %w;
- and the catalytic hydrotreatment is carried out under such conditions as to satisfy the relation:
- ##EQU6## where ##EQU7## d=the RCT of the mixture of asphaltic bitumen I and asphaltic bitumen II, e=the RCT of the atmospheric residue with an initial boiling point of T.sub.1 .degree.C. of the hydrotreated product, and
- r=the number of pbw of asphaltic bitumen II per 100 pbw of asphaltic bitumen I present in the feed mixture.
Dependencies are inferred from the claim text.