Polymerization catalyst, process for preparing, and use for ethylene homopolymerization

A process for preparing a catalyst composition which comprises

• (A) forming, a precursor composition of the formula
• Mg.sub.m Ti.sub.1 (OR).sub.n X.sub.p [ED].sub.q
• wherein
• R is C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical, or COR' wherein R' is a C.sub.1 to C.sub.14 aliphatic or aromatic hydrocarbon radical,
• X is selected from the group consisting of Cl, Br, I, or mixtures thereof,
• ED is an electron donor compound,
• m is .gtoreq.0.5 to .ltoreq.56
• n is 0 or 1
• p is .gtoreq.6 to .ltoreq.116 and
• q is .gtoreq.2 to .ltoreq.85
• by dissolving at least one magnesium compound and at least one titanium compound in at least one electron donor compound so as to thereby form a solution of said precursor composition in said electron donor compound, and recovering said precursor composition from said solution,
• said magnesium compound having the structure MgX.sub.2,
• said titanium compound having the structure Ti(OR).sub.a X.sub.b
• wherein a is 0 or 1, b is 2 to 4 inclusive and a+b=3 or 4
• said electron donor compound being a liquid organic compound in which said magnesium compound and said titanium compound are soluble and which is selected from the group consisting of alkyl esters of aliphatic and aromatic carboxylic acids, aliphatic ethers, cyclic ethers and aliphatic ketones,
• and said magnesium compound, said titanium compound and said electron donor compound being employed in such amounts as to satisfy the values of m, n, p and q,
• (B) diluting said precursor composition with about 1 to 10 parts by weight, per part by weight of said precursor composition, of at least one inert carrier material,
• (C) partially activating the precursor composition outside the polymerization zone in a hydrocarbon slurry with >0 to <10 mols of activator compound per mol of titanium in said precursor composition, said activator compound having the structure
• Al(R").sub.c X'.sub.d H.sub.e
• wherein X' is Cl or OR'", R" and R'" are the same or different and are C.sub.1 to C.sub.14 saturated hydrocarbon radicals, d is 0 to 1.5, e is 1 or 0 and c+d+e=3, and
• (D) completely activating the precursor composition in a fluid bed polymerization zone with .gtoreq.10 to about 400 mols of said activator compound in the absence of a solvent so as to avoid the need for drying the fully active catalyst to remove the solvent therefrom.