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US 4,395,266 AGranted
Stabilized water-in-mineral oil emulsion
AssigneeInternationale Octrooi Maatschappij "Octropa" B.V.
InventorKong W. Han
Life of this patent
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Abstract
A stabilized water-in-mineral oil emulsion containing a finely divided stabilizer which is substantially undissolved in the constituent phases of the emulsion and forms an interface between said phases. The emulsion is produced starting from water, mineral oil, a surfactant and a stabilizer, which is preferably formed in situ. The emulsion can be used as fuel and displays an improved combustion.
Claims15
Water-in-mineral oil emulsion comprising:
- (a) 1-50 vol.% of water,
- (b) 99-50 vol.% of a mineral oil selected from the group consisting of gasoline, kerosene, diesel oil, heavy gasoline and fuel oil,
- (c) an effective proportion of a surfactant, and
- (d) a finely divided stabilizer which is substantially undissolved in the constituent phases of the emulsion and forms an interface between said phases, said stabilizer being a compound comprising at least one polar group having a dipole or being capable of forming a hydrogen bridge and at least 2 non-polar hydrocarbon groups containing at least 8 carbon atoms, said compound being selected from the group consisting of (i) a di- or tri-amide obtained by reacting a fatty acid with a compound containing 2 or 3 amino groups, (ii) the product obtained by reacting a mono-, di- and/or tri-alkanolamine soap derived from a natural or synthetic fatty acid and a quaternary ammonium salt comprising at least on substituent containing at least 8 carbon atoms, whereby the remaining substituents may consist of alkyl groups containing 1-3 carbon atoms, and (iii) a polymer obtained by reacting a polyalkyl anhydride with a compound containing at least 2 amino groups.
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A process for preparing a water-in-mineral oil emulsion, which comprises producing an emulsion starting from:
- (a) 1-50 vol.% of water,
- (b) 99-50 vol.% of a mineral oil selected from the group consisting of gasoline, kerosene, diesel oil, heavy gasoline and fuel oil,
- (c) an effective proportion of a surfactant, and
- (d) a finely divided stabilizer which is substantially undissolved in the constituent phases of the emulsion and forms an interface between said phases, said stabilizer being a compound comprising at least one polar group having a dipole of being capable of forming a hydrogen bridge and at least 2 non-polar hydrocarbon groups containing at least 8 carbon atoms, said compound being selected from the group consisting of (i) a di- or tri-amide obtained by reacting a fatty acid with a compound containing 2 or 3 amino groups, (ii) the product obtained by reacting a mono-, di- and/or tri-alkanolamine soap derived from a natural or synthetic fatty acid and a quaternary ammonium salt comprising at least one substituent containing at least 8 carbon atoms, whereby the remaining substituents may consist of alkyl groups containing 1-3 carbon atoms, and (iii) a polymer obtained by reacting a polyalkyl anhydride with a compound containing at least 2 amino groups, said stabilizer being formed in situ.
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Dependencies are inferred from the claim text.