Process for hydrogenating aldehydes
AssigneeGulf Research & Development Company
InventorsRoger F. Vogel, George Marcelin, Harold E. Swift
Life of this patent
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Abstract
A process for hydrogenating an unsaturated organic compound which comprises contacting the same with hydrogen in the presence of a catalyst composed of a support containing (1) at least one Group IIA metal compound selected from the group consisting of magnesium, calcium, strontium and barium compounds, (2) alumina and (3) aluminum phosphate carrying nickel thereon.
Claims23
A process for hydrogenating an aliphatic aldehyde having from two to 20 carbon atoms which comprises contacting the same with hydrogen in the presence of a catalyst composed of about three to about 60 weight percent nickel mounted on an amorphous support containing (1) at least one Group IIA metal compound selected from the group consisting of magnesium, calcium, strontium and barium compounds, (2) alumina and (3) aluminum phosphate, such support having an average pore radius of from about 10 A to about 300 A, a surface area ranging from about 80 m.sup.2 /g to about 350 m.sup.2 /g and a pore volume of from about 0.33 cc/g to about 1.5 cc/g, said Group IIA metal compound being present in an amount ranging from about two to about 35 mole percent, alumina in an amount ranging from about 15 to about 60 mole percent and aluminum phosphate in an amount ranging from about 25 to about 80 mole percent wherein said unsaturated organic compound is passed over said catalyst at a liquid hourly space velocity of about 1.0 to about 12 while maintaining in the reaction zone a temperature of about 30.degree. to about 200.degree. C. and a hydrogen partial pressure of about 0 to about 500 pounds per square inch gauge.
Dependencies are inferred from the claim text.