Quaternary ammonium functional silicon compounds
AssigneeSWS Silicones Corporation
InventorsEugene R. Martin, Jeffrey A. Tripp
Life of this patent
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Abstract
Quaternary ammonium functional silicon compounds are prepared by reacting carboxylic acid functional quaternary ammonium compounds with aminofunctional silicon compounds. These quaternary ammonium functional silicon compounds are antistatic finishes for textiles.
Claims18
A process for preparing quaternary ammonium functional silicon compounds which comprises reacting a carboxylic acid functional quaternary ammonium compound selected from the group consisting of compounds having the formulas ##STR10## with an aminofunctional silicon compound selected from the group consisting of
- (a) Silanes having the formula ##STR11## (b) Siloxanes having at least one unit of the formula ##STR12## (c) and mixtures thereof, at a temperature of from 0.degree. up to about 175.degree. C., in which R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, R.sup.1 is a hydrocarbonoxy radical having the formula --(C.sub.n H.sub.2n O).sub.r, R.sup.2 is a divalent hydrocarbon radical selected from the group consisting of (CH.sub.2).sub.y, CH.dbd.CH and cyclic divalent hydrocarbon radicals selected from the group consisting of C.sub.6 H.sub.4, C.sub.6 H.sub.8, C.sub.6 H.sub.10, and C.sub.10 H.sub.6, R.sup.3 is a divalent hydrocarbon radical having from 2 to 10 carbon atoms, R.sup.4 is selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having from 3 to 10 carbon atoms, X is an anionic radical, a is a number of from 1 to 4, b is 0, 1 or 2, c is 0, 1, 2 or 3, e is a number of from 1 to 3, f is a number of from 0 to 3, in which the sum of a+f cannot exceed 4, g is a number of from 0 to 2, in which the sum of e+g cannot exceed 3, n is 2, 3 or 4, r is a number of from 1 to 50 and y is a number of from 0 to 10.
A process for imparting antistatic properties to textile materials which comprises applying to the textile materials a composition obtained from the reaction of a carboxylic acid functional quaternary ammonium compound selected from the group consisting of compounds having the formulas ##STR17## with an aminofunctional silicon compound selected from the group consisting of
- (a) Silanes having the formula ##STR18## (b) Siloxanes having at least one unit of the formula ##STR19## (c) and mixtures thereof, at a temperature of from 0.degree. up to about 175.degree. C., in which R is a monovalent hydrocarbon radical having from 1 to 22 carbon atoms, R.sup.1 is a hydrocarbonoxy radical having the formula --(C.sub.n H.sub.2n O).sub.2, R.sup.2 is a divalent hydrocarbon radical selected from the group consisting of (CH.sub.2).sub.y, CH.dbd.CH and a cyclic divalent hydrocarbon radical selected from the group consisting of C.sub.6 H.sub.4, C.sub.6 H.sub.8, C.sub.6 H.sub.10, and C.sub.10 H.sub.6, R.sup.3 is a divalent hydrocarbon radical having from 2 to 10 carbon atoms, R.sup.4 is selected from the group consisting of a saturated divalent hydrocarbon radical having up to 10 carbon atoms, a divalent hydrocarbonoxy radical in which the oxygen is in the form of an ether linkage and an unsaturated divalent hydrocarbon radical having from 3 to 10 carbon atoms, X is an anionic radical, a is a number of from 1 to 4, b is 0, 1 or 2, c is 0, 1, 2 or 3, e is a number of from 1 to 3, f is a number of from 0 to 3, in which the sum of a+f cannot exceed 4, g is a number of from 0 to 2, in which the sum of e+g cannot exceed 3, n is 2, 3 or 4, r is a number of from 1 to 50 and y is a number of from 0 to 10 and thereafter heating the treated textile material at an elevated temperature.
Dependencies are inferred from the claim text.