Coating composition
AssigneesSumitomo Chemical Company, Limited, Nippon Sheet Glass Co., Ltd.
InventorsAkira Fujioka, Kazuo Sakiyama, Akio Takigawa, Motoaki Yoshida
Life of this patent
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Abstract
A coating composition, which comprises: (A) at least one hydrolyzate selected from the group of epoxy group-containing silicon compounds, (B) at least one member selected from the group consisting of hydrolyzates of organic silicon compounds, colloidal silica and organic titanium compounds, and (C) a curing catalyst.
Claims12
A transparent, abrasion-resistant coating composition having high adhesiveness for transparent polymers, which comprises:
- as component (A), at least one hydrolyzate selected from the group of epoxy group-containing silicon compounds represented by the general formula (1):
- ##STR10## wherein, R.sup.1 stands for an organic group containing an epoxy group, R.sup.2 for hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms or vinyl group, R.sup.3 for a hydrocarbon group having 1 to 5 carbon atoms, alkoxyalkyl group or acyl group having 1 to 4 carbon atoms, a for an integer of 1 to 3 and b for an integer of 0 to 2, providing that a+b.ltoreq.3 is satisfied, said one hydrolyzate being used in an amount of 100 parts by weight (of solids;
- calculated as ##EQU11## as component (B), at least one member selected from the group consisting of hydrolyzates of organic silicon compounds represented by the general formula (2):
- R.sub.c.sup.4 --Si--(OR.sup.5).sub.4-c ( 2)
- wherein, R.sup.4 stands for a hydrocarbon group having 1 to 6 carbon atoms, vinyl group, methacryloxy group, amino group, mercapto group, or organic group containing fluorine or chlorine, R.sup.5 for a hydrocarbon group having 1 to 5 carbon atoms, alkoxyalkyl group or acyl group having 1 to 4 carbon atoms and c for an integer of 0 to 3;
- colloidal silica and organic titanium compounds, said one member being used in an amount within the range of from 1 to 567 parts by weight (of solids, calculated as R.sub.c.sup.4 --Si--O.sub.(4-c)/2 in the case of an organic silicon compound represented by the general formula (2), as SiO.sub.2 in the case of colloidal silica or as R.sub.d.sup.6 --Ti--O.sub.(4-d)/2 in the case of an organic titanium compound, wherein R.sup.6 stands for an unhydrolyzed group containing no hydroxy group and d for an integer of 1 to 4);
- and as component (C), a curing catalyst selected from the group consisting of ammonium perchlorate and ammonium chloride.
A transparent, abrasion-resistant coating composition having high adhesiveness for transparent polymers, which comprises:
- as component (A), at least one hydrolyzate selected from the group of epoxy group-containing silicon compounds represented by the general formula (1):
- ##STR11## wherein, R.sup.1 stands for an organic group containing an epoxy group, R.sup.2 for hydrogen atom, a hydrocarbon group having 1 to 6 carbon atoms or vinyl group, R.sup.3 for a hydrocarbon group having 1 to 5 carbon atoms, alkoxyalkyl group or acyl group having 1 to 4 carbon atoms, a for an integer of 1 to 3 and b for an integer of 0 to 2, providing that a+b.ltoreq.3 is satisfied, said one hydrolyzate being used in an amount of 100 parts by weight (of solids, calculated as ##EQU12## as component (B), at least one member selected from the group consisting of hydrolyzates of organic silicon compounds represented by the general formula (2):
- R.sub.c.sup.4 --Si--(OR.sup.5).sub.4-c ( 2)
- wherein, R.sup.4 stand for a hydrocarbon group having 1 to 6 carbon atoms, vinyl group, methacryloxy group, amino group, mercapto group, or organic group containing fluorine or chlorine, R.sup.5 for a hydrocarbon group having 1 to 5 carbon atoms, alkoxyalkyl group or acyl group having 1 to 4 carbon atoms and c for an integer of 0 to 3, used in an amount within the range of 56 to 550 parts and colloidal silica used in an amount within the range of from 4 to 334 parts, (of solids, calculated as R.sub.c.sup.4 --Si--(OR.sup.5).sub.(4-c)/2 in the case of an organic silicon compound represented by the general formula (2), and as SiO.sub.2 in the case of colloidal silica), providing that the total amounts of the members of component (B) fall within the range of from 60 to 567 parts;
- and as component (C), a curing catalyst selected from the group consisting of ammonium perchlorate and ammonium chloride.
Dependencies are inferred from the claim text.