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US 4,393,215 AGranted
Cleavage of dialkoxyketoxime
AssigneeAllied Corporation
InventorsMilorad M. Rogic, Bryce C. Oxenrider
Life of this patent
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Abstract
Dialkoxyketoximes such as dimethoxycyclohexanone cleave with halogen and water under basic conditions to yield a series of products having an ester functionality and another functionality which is oximohalide, nitrile oxide or furoxan, depending upon the base strength and/or work-up conditions. Each of those products can be further reacted with sulfur dioxide to produce an adduct, from which an isocyanate is derived. Both the adduct and the isocyanate retain the ester functionality.
Claims6
A process of cleaving a dialkoxyketoxime which comprises reacting in the liquid phase a dialkoxyketoxime of the formula:
- ##STR13## wherein Y and Z are each independently linear or branched alkyl and R and R' are each independently linear or branched alkyl or are together --(CH.sub.2).sub.n -- where n is an integer from 3 to 10, with a halogen selected from elemental chlorine and elemental bromine in the presence of a base and at least an equimolar amount of water under conditions forming a product selected from the group consisting of an oximinohalide of the formula:
- ##STR14## where R, R' and Z' are as defined above and X is Cl or Br;
- a nitrile oxide of the formula:
- ##STR15## a furoxan of the formula:
- ##STR16## and mixtures thereof.
2 more elements
Dependencies are inferred from the claim text.