Thermoplastic polyurethanes prepared by reacting polyisocyanate, polyester polyol, cycloaliphatic diol and a monofunctional chain-terminating compound

Abstract

Novel polyurethanes especially suited for applications requiring initial heat resistance in a non-alcohol, non-exotic solvent system such as methyl ethyl ketone and having peel strengths of at least 5 pounds per linear inch (pli) uncrosslinked at about 180.degree. to about 200.degree. F., optionally containing crosslinkers, and which are typically used in the automobile industry, are described. The new polyurethanes are substantially free of reactive isocyanate and hydroxyl groups and comprise the reaction product of (a) at least one polyisocyanate having at least two reactive isocyanate groups; (b) at least one polyester polyol having at least two hydroxyl groups; (c) at least one cycloaliphatic diol chain-extending agent; and (d) at least one monofunctional isocyanate-reactive chain-terminating compound; said polyisocyanate being present in an excess amount with respect to said polyester polyol and said cycloaliphatic diol; said monofunctional isocyanate-reactive compund being present in an amount sufficient to ensure reaction of excess isocyanate groups; said polyester polyol comprising the reaction product of (i) at least one saturated acyclic, cyclic or aromatic monomeric or polymeric polyol having at least two hydroxy groups; (ii) from 30 to 100 mole percent terephthalic acid; and (iii) from 70 to 0 mole percent of at least one saturated or unsaturated acyclic, cyclic or aromatic carboxylic acid, other than terephthalic acid, having at least two carboxyl groups; said polyurethane having a molecular weight of at least 20,000.

Dependencies are inferred from the claim text.