Cationic phthalocyanine dyes
AssigneeBASF SE
InventorsManfred Patsch, Manfred Ruske, Erwin Hahn
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AssigneeBASF SE
InventorsManfred Patsch, Manfred Ruske, Erwin Hahn
Estimating the term…
Cationic phthalocyanine dyes of the formula ##STR1## where Pc is an (m+n+p)-valent phthalocyanine radical, R.sup.1 is H or alkyl, R.sup.2 and R.sup.3 independently of one another are alkyl, hydroxyalkyl, cycloalkyl, benzyl, phenyl or tolyl, or ##STR2## is pyrrolidinyl, imidazolyl, 2-ethyl-4-methylimidazolyl, morpholinyl, piperazinyl or N'-alkylpiperazinyl, or is ##STR3## R.sup.4 is H or methyl, R.sup.5 is alkyl, hydroxyalkyl or benzyl, X.sup..sym. is one equivalent of an anion, M.sup..crclbar. is one equivalent of a cation, z is 1 or 2, p is 0 or 1, m is 0 or 1 and n is from 1 to 4, and 1<(m+n)<4, are readily or highly soluble in water and very substantive on paper, and accordingly are particularly suitable for dyeing and printing paper. Paper dyed with (I) has very good bleeding fastness, and a colorless effluent is obtained when paper is wet-end dyed.
A cationic phthalocyanine dye of the formula ##STR36## where Pc is an (n+m+p)-valent radical of a phthalocyanine, R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.14 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, C.sub.5 -C.sub.8 -cycloalkyl, benzyl, phenyl or tolyl, or ##STR37## is a pyrrolidine, imidazole, 2-ethyl-4-methylimidazole, morpholine, piperazine or N'--C.sub.1 -C.sub.4 -alkylpiperazine radical, or is ##STR38## R.sup.4 is hydrogen or methyl, R.sup.5 is C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.4 -hydroxyalkyl, chlorine-substituted C.sub.2 -C.sub.4 -hydroxyalkyl or benzyl, X.sup..crclbar. is one equivalent of an anion, M.sup..sym. is one equivalent of a cation, z is a 1 or 2, p is 0 or 1, m is 0 or 1 and n is 1, 2, 3 or 4, and 1<(m+n)<4.
A cationic phthalocyanine dye of the formula:
Dependencies are inferred from the claim text.