Chlorine cell design for electrolyte series flow
AssigneeThe Dow Chemical Company
InventorJohn R. Pimlott
Life of this patent
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Abstract
Chlor-alkali electrolytic membrane cells are provided with means for flowing catholyte from cell-to-cell sequentially, and means for flowing anolyte from cell-to-cell sequentially.
Claims12
In a bank or series of chlor-alkali electrolytic cells, wherein each cell comprises at least one electrode pair separated by a cation permselective, substantially hydraulically impermeable membrane, with means for flowing catholyte from cell-to-cell sequentially,
- the embodiment in which the means for flowing catholyte from cell-to-cell comprises, in operable combination,
- entry means for adding water or dilute caustic to the catholyte portion of a first cell of the bank or series,
- flow means for directing gas-lifted catholyte liquor from said first cell to a de-gassing compartment above said cathodes,
- flow means for directing at least a portion of the de-gassed catholyte to a point below the surface of the catholyte liquor in the next successive cell while allowing at least a portion of the de-gassed catholyte to re-enter the cell from which it came,
- flow means for directing gas-lifted catholyte liquor from said next successive cell and each additional successive cell in the series thereafter, to a degassing compartment above the cathodes, at least a portion of the de-gassed catholyte of each cell being directed to a next successive cell while allowing at least a portion of the de-gassed catholyte to re-enter the cell from which it came,
- flow means for directing de-gassed catholyte liquor from the last cell of the bank or series, and
- flows means for removing cell gasses from the de-gassing compartment.
In a bank or series of chlor-alkali electrolytic cells, wherein each cell comprises at least one electrode pair separated by a cation permselective, substantially hydraulically impermeable membrane, with means for flowing anolyte from cell-to-cell sequentially,
- the embodiment in which the means for flowing anolyte from cell-to-cell comprises, in operable combination,
- entry means for adding alkali metal chloride solution to the anolyte portion of a first cell of the bank or series,
- flow means for directing gas-lifted anolyte liquor from said first cell to a de-gassing compartment above said anodes,
- flow means for directing at least a portion of the de-gassed anolyte to a point below the surface of the anolyte liquor in the next successive cell while allowing at least a portion of the de-gassed anolyte to re-enter the cell from which it came,
- flow means for directing gas-lifted anolyte liquor from said next successive cell and each additional successive cell in the series thereafter, to a de-gassing compartment above the anodes, at least a portion of the de-gassed anolyte of each cell being directed to a next successive cell while allowing at least a portion of the de-gassed anolyte to re-enter the cell from which it came,
- flow means for directing de-gassed anolyte liquor from the last cell of the bank or series, and
- flow means for removing cell gasses from the de-gassing compartments.
Dependencies are inferred from the claim text.