Photographic recording material and non-diffusing compounds to be used in the material which contains a photographically active group which can be split off
AssigneeAgfa-Gevaert
InventorsGunter Renner, Erich Wolff
Life of this patent
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Abstract
Novel non-diffusing reducible compounds of formula I which under alkaline development conditions release a diffusible photographically useful compound are of use in color diffusion transfer processes. ##STR1## R.sup.0 completes a ring system; E represents a reducible group; W reduces the electron density in the position of E so that E is reducible under photographic development conditions; GR.sup.1 represents a group from which photographically useful compound R.sup.1 is released; XR.sup.2 represents a group that by reduction of E is activated to cooperate with GR.sup.1 in an intramolecular reaction with release of R.sup.1.
Claims7
Photographic recording material having at least one light-sensitive silver halide emulsion layer and in association with said silver halide emulsion layer, a non-diffusing reducible compound which can be split to release a diffusible photographically useful compound, the non-diffusing reducible compound corresponding to the following formula I ##STR17## in which the substituents W, XR.sup.2, G--R.sup.1 and E may be arranged in any positions in relation to each other and in which:
- R.sup.0 represents the atoms required to complete a ring system comprising at least one aromatic or heteroaromatic ring;
- W represents a group which reduces the electron density in the ring at the position of E and is selected from the group consisting of a halogen atom, a cyano group, a nitro group, a nitroso group, a trifluoromethyl group, a quaternary ammonium group and an acyl group;
- m represents an integer of from 1 to 3;
- G represents a group from which R.sup.1 can be split off under photographic development conditions;
- R.sup.1 represents the residue of a diffusible photographically active compound;
- X represents an oxygen atom, a sulfur atom or the group --NR.sup.3 --;
- R.sup.2 represents hydrogen or a group which can be split off in alkaline medium, and
- E represents a reducible substituent selected from the group consisting of ##STR18## R.sup.3 represents hydrogen, alkyl, aryl, a heterocyclic group or aralkyl, and the compound of formula I contains at least one substituent conferring diffusion resistance.
Dependencies are inferred from the claim text.