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US 4,323,636 AGranted
Photosensitive block copolymer composition and elements
AssigneeE. I. Du Pont de Nemours and Company
InventorGwendyline Y. Y. T. Chen
Life of this patent
Estimating the term…
Abstract
Compatible photosensitive compositions, and elements made therefrom, comprising a solvent-soluble, thermoplastic, elastomeric, block copolymer, a nongaseous ethylenically unsaturated compound, and an addition polymerization initiator activatable by actinic light are useful in preparing printing plates, particularly flexographic printing plates, and other relief images.
Claims10
A compatible photosensitive, elastomeric composition comprising:
- (1) at least 30% by weight of at least one solvent-soluble, thermoplastic, elastomeric block copolymer containing at least two thermoplastic, nonelastomeric polymer blocks having a glass transition temperature above 25.degree. C. and an average molecular weight of 2000-100,000, and between said thermoplastic, nonelastomeric polymer blocks an elastomeric polymer block having a glass transition temperature below 10.degree. C. and an average molecular weight of about 25,000 to 1,000,000, the thermoplastic, nonelastomeric polymer blocks being the terminal blocks of said copolymer and being connected by said elastomeric polymer block,
- (2) at least 1% by weight of at least one addition-polymerizable, ethylenically unsaturated compound having a boiling point at normal pressure over 100.degree. C. taken from the group consisting of t-butyl acrylate, N,N-diethylaminoethyl acrylate, 1,4-butanediol diacrylate, hexamethylene glycol diacrylate, decamethylene glycol diacrylate, 2,2-dimethylolpropane diacrylate, tripropylene glycol diacrylate, 2,2-di(p-hydroxyphenyl)-propane diacrylate, 2,2-di(p-hydroxyphenyl)-propane dimethacrylate, polyoxyethyl-2,2-di(p-hydroxyphenyl)-propane dimethacrylate, butylene glycol dimethacrylate, hexamethylene glycol dimethacrylate, 2,2,4-trimethyl-1,3-pentanediol dimethacrylate, 1-phenylethylene-1,2-dimethacrylate, and triethyleneglycol diacrylate said addition-polymerizable, ethylenically unsaturated compound being compatible with the thermoplastic-elastomeric block copolymer component which is soluble in or which forms a solution with the ethylenically unsaturated compound;
- and
- (3) a polymerization-effective amount of polymerization initiator activatable by actinic radiation.
1 more element
A compatible photosensitive, elastomeric composition in the absence of solvent comprising:
- (1) at least 30% by weight of at least one solvent-soluble, thermoplastic, elastomeric block copolymer containing at least two thermoplastic, nonelastomeric polymer blocks having a glass transition temperature above 25.degree. C. and an average molecular weight of 2000-100,000, and between said thermoplastic, nonelastomeric polymer blocks an elastomeric polymer block having a glass transition temperature below 10.degree. C. and an average molecular weight of about 25,000 to 1,000,000, the thermoplastic, nonelastomeric polymer blocks being the terminal blocks of said copolymer and being connected by said elastomeric polymer block,
- (2) at least 1% by weight of at least one addition-polymerizable, ethylenically unsaturated compound having a boiling point at normal pressure over 100.degree. C. taken from the group consisting of t-butyl acrylate, N,N-diethylaminoethyl acrylate, 1,4-butanediol diacrylate, hexamethylene glycol diacrylate, decamethylene glycol diacrylate, 2,2-dimethylolpropane diacrylate, tripropylene glycol diacrylate, 2,2-di(p-hydroxyphenyl)-propane diacrylate, 2,2-di(p-hydroxyphenyl)-propane dimethacrylate, polyoxyethyl-2,2-di(p-hydroxyphenyl)-propane dimethacrylate, butylene glycol dimethacrylate, hexamethylene glycol dimethacrylate, 2,2,4-trimethyl-1,3-pentanediol dimethacrylate, 1-phenylethylene-1,2-dimethacrylate, and triethyleneglycol diacrylate said addition-polymerizable, ethylenically unsaturated compound being compatible with the thermoplastic-elastomeric block copolymer component which is soluble in or which forms a solution with the ethylenically unsaturated compound;
- and
- (3) a polymerization-effective amount of polymerization initiator activatable by actinic radiation.
1 more element
Dependencies are inferred from the claim text.