Photocurable compositions
AssigneeCiba-Geigy Corporation
InventorGodwin Berner
Life of this patent
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Abstract
The use of photo-initiators of the formula I or II ##STR1## in which n is 1 or 2, Ar is a monovalent or divalent aromatic radical, X is a tertiary amino group, a hydroxyl or ether group or a siloxy group, R.sup.1 and R.sup.2 are alkyl, substituted alkyl, alkenyl, cycloalkyl or phenylalkyl or together are alkylene or oxa- or aza-alkylene and R.sup.3 is a direct bond or a divalent aliphatic, cycloaliphatic or aromatic radical, in combination with light stabilizers from the category of the polyalkylpiperidine derivatives in the photopolymerization of ethylenically unsaturated compounds results in polymers with high stability to light and low yellowing.
Claims8
A photocurable composition consisting of (a) one or more ethylenically unsaturated, photocurable compounds, (b) at least one photo-initiator of the formula I or II ##STR4## in which n is 1 or 2 and, if n is 1, Ar is unsubstituted phenyl or phenyl substituted by one or more of the radicals F, Cl, Br, C.sub.1 -C.sub.12 alkyl, -OAlk, phenyl, -Ophenyl, --SAlk, --SCH.sub.2 CH.sub.2 OH or -Sphenyl, or indanyl or tetrahydronaphthyl, and Alk is a lower alkyl radical having 1-4 C atoms, and if n is 2 Ar is C.sub.6 -C.sub.12 arylene or a group -phenylene-T-phenylene-, in which T is --O--, --S--, --CH.sub.2 -- or --CH.sub.2 CH.sub.2 --, X is one of the groups --NR.sup.4 R.sup.5, --OR.sup.6 or --OSiR.sup.7 (R.sup.8).sub.2, R.sup.1 is unsubstituted C.sub.1 -C.sub.8 alkyl or C.sub.1 -C.sub.8 alkyl substituted by --OH, OAlk, C.sub.2 -C.sub.8 acyloxy, --NR.sup.4 R.sup.5, --COOAlk or --CN, or C.sub.3 -C.sub.4 alkenyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.7 -C.sub.9 phenylalkyl, R.sup.2 has one of the meanings defined for R.sup.1 or together with R.sup.1 is C.sub.2 -C.sub.8 alkylene or C.sub.3 -C.sub.9 oxa- or aza-alkylene, R.sup.3 is a direct bond, C.sub.1 -C.sub.6 alkylene, C.sub.2 -C.sub.6 oxa-alkylene, C.sub.2 -C.sub.6 thia-, S-oxothia- or S-dioxothiaalkylene, phenylene, diphenylene or a group -phenylene-T-phenylene-, or together with the two substituents R.sup.2 and the two C atoms to which these substituents are bonded forms a cyclopentane, cyclohexane, endomethylenecyclohexane or cyclohexane ring, R.sup.4 is C.sub.1 -C.sub.12 alkyl or C.sub.2 -C.sub.4 alkyl which is substituted by --OH or OAlk, R.sup.5 is C.sub.1 -C.sub.12 alkyl or C.sub.2 -C.sub.4 alkyl which is substituted by OH or OAlk, or together with R.sup.4 is C.sub.4 -C.sub.5 alkylene, which can be interrupted by --O-- or --NR.sup.9 --, R.sup.6 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.8 alkyl substituted by Cl, Br, OH, OAlk, SAlk, C.sub.2 -C.sub.8 acyloxy, --COOAlk, --CONHAlk, --CON(Alk).sub.2 or CN, or C.sub.3 -C.sub.5 alkenyl, cyclohexyl, benzyl, unsubstituted phenyl or phenyl substituted by Cl or Alk, or 2-tetrahydropyranyl, R.sup.7 and R.sup.8 are identical or different and are C.sub.1 -C.sub.4 alkyl or phenyl and R.sup.9 is C.sub.1 -C.sub.4 alkyl, --CH.sub.2 CH.sub.2 CN or --CH.sub.2 CH.sub.2 COOAlk, and (c) at least one light stabiliser from the category of the polyalkylpiperidine derivatives.
Dependencies are inferred from the claim text.