Dissolution of metals utilizing an aqueous H.sub.2 O.sub.2 -H.sub.2 SO.sub.4 -thioamide etchant
AssigneeDart Industries Inc.
InventorsSilvester P. Valayil, Moenes L. Elias
Life of this patent
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Abstract
Improved metal dissolution rates are obtained when using a solution containing sulfuric acid, hydrogen peroxide and a catalytic amount of a thioamide having the general formula ##STR1## wherein R is an aryl or a heterocyclic group.
Claims19
A method of metal dissolution which comprises contacting a metal with an aqueous solution containing from about 0.2 to about 4.5 gram moles per liter of sulfuric acid, from about 0.25 to about 8 gram moles per liter of hydrogen peroxide and a catalytically effective amount of a thioamide additive having the general formula ##STR3## wherein R is either an aryl or a heterocyclic group and the aryl group is selected from phenyl, alkyl substituted phenyl groups containing from 7 to 10 carbon atoms and amino substituted phenyl groups and the heterocyclic group is selected from those containing at least one nitrogen atom in the ring structure.
A composition for metal dissolution comprising an aqueous solution of from about 2.0 to about 4.5 gram moles per liter of sulfuric acid, from about 0.25 to about 8 gram moles per liter of hydrogen peroxide and a catalytically effective amount of a thioamide additive having the general formula ##STR4## wherein R is either an aryl or a heterocyclic group and the aryl group is selected from phenyl, alkyl substituted phenyl groups containing from 7 to 10 carbon atoms and amino substituted phenyl groups and the heterocyclic group is selected from those containing at least one nitrogen atom in the ring structure.
Dependencies are inferred from the claim text.