Dissolution of metals utilizing an aqueous H.sub.2 SO.sub.4 -H.sub.2 O.sub.2 -polysulfide etchant
AssigneeDart Industries Inc.
InventorsSilvester P. Valayil, Moenes L. Elias
Life of this patent
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Abstract
Improved metal dissolution rates are obtained when using a solution containing sulfuric acid, hydrogen peroxide and a catalytic amount of a polysulfide compound having the general formula ##STR1## wherein R is a hydroxyl group, a carboxyl group, a sulfonic acid group or a sulfonic acid salt group, each X independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, each Y independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, m is an integer from 1 to 18, and n is an integer from 2 to 5.
Claims29
A method of metal dissolution which comprises contacting a metal with an aqueous solution containing from about 0.2 to about 4.5 gram moles per liter of sulfuric acid, from about 0.25 to about 8 gram moles per liter of hydrogen peroxide and a catalytically effective amount of a polysulfide compound additive having the general formula ##STR3## wherein R is a hydroxyl group, a carboxyl group, a sulfonic acid group or a sulfonic acid salt group, each X independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, each Y independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, m is an integer from 1 to 18, and n is an integer from 2 to 5.
A composition for metal dissolution comprising an aqueous solution of from about 2.0 to about 4.5 gram moles per liter of sulfuric acid, from about 0.25 to about 8 gram moles per liter of hydrogen peroxide and a catalytically effective amount of a polysulfide compound additive having the general formula ##STR4## wherein R is a hydroxyl group, a carboxyl group, a sulfonic acid group or a sulfonic acid salt group, each X independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, each Y independently from each other can be hydrogen, hydroxyl or C.sub.1 -C.sub.4 alkyl, m is an integer from 1 to 18, and n is an integer from 2 to 5.
Dependencies are inferred from the claim text.