Photo-polymerization and development process which produces dot-etchable material
AssigneeE. I. Du Pont de Nemours and Company
InventorsMartin D. Bratt, Abraham B. Cohen
Life of this patent
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Abstract
Photopolymerizable elements are described comprising a sheet support, a photopolymerizable layer having a thickness of, at most, 0.0006 inch (0.015 mm.) and an optical density of at least 3.0 in the actinic region. Resist images made from these elements may be etched by a process of chemically undercutting the image areas and then spraying or rubbing them. The elements are useful as contact speed lithographic films and for other graphic arts applications.
Claims16
A process of image reproduction which comprises imagewise exposing to actinic radiation a photopolymerizable element which comprises a support bearing a photopolymerizable layer containing actinic radiation absorbing material and having a maximum thickness of 0.015 mm and an optical density in the actinic region of at least 3.0, said photopolymerizable layer being the outermost layer of the element or being contiguous to a removable cover sheet or an overcoat layer which is at least partially soluble in or permeable to a solvent for the photopolymerizable layer, said exposure being through the outermost surface of the photopolymerizable layer or removable cover sheet or overcoat layer, when present, and wherein said exposure produces image areas having a hardened upper skin which rests on a softer undervolume having a lesser degree of polymerization or hardening, and then developing by removing the unexposed areas of the layer to form an image.
A process of image reproduction which comprises (1) imagewise exposing to actinic radiation a photopolymerizable element which comprises a support bearing a photopolymerizable layer containing actinic radiation absorbing material and having a maximum thickness of 0.015 mm and an optical density in the actinic region of at least 3.0, said photopolymerizable layer being the outermost layer of the element or being contiguous to a removable cover sheet or an overcoat layer which is at least partially soluble in or permeable to a solvent for the photopolymerizable layer, said exposure being through the outermost surface of the photopolymerizable layer or removable cover sheet or overcoat layer, when present, and wherein said exposure produces image areas having a hardened upper skin which rests on a softer undervolume having a lesser degree of polymerization or hardening, (2) developing by removing the unexposed areas of the layer, and (3) reducing the size of exposed image areas by undercutting the edges of the hardened upper skin with a solvent for the softer undervolume and removing the hardened polymer and the edges of the hardened upper skin by mechanical action on the image bearing surface.
Dependencies are inferred from the claim text.