Photographic emulsions and elements containing agel crystals forming epitaxial junctions with AgI crystals
AssigneeEastman Kodak Company
InventorJoe E. Maskasky
Life of this patent
Estimating the term…
Abstract
Photographic emulsions and elements are disclosed containing composite silver halide crystals. The composite crystals are comprised of multi-faceted, radiation-receptive silver iodide crystals having a minimum mean diameter of at least 0.1 micron and silver chloride crystals forming epitaxial junctions with the silver iodide crystals. At least half of the facets of the silver iodide crystals are substantially free of epitaxial silver chloride. The silver chlorides are limited to less than 75 mole percent, based on the total silver halide forming the composite crystals.
Claims20
A photographic emulsion comprised of a photographic vehicle as a continuous phase and, as a discrete phase, radiation-sensitive composite silver halide crystals comprised of
- multi-faceted, radiation-receptive silver iodide crystals having a minimum mean diameter of at least 0.1 micron,
- silver chloride crystals forming epitaxial junctions with the silver iodide crystals,
- at least half of the facets of the silver iodide crystals being substantially free of epitaxial silver chloride, and
- silver chloride being limited to less than 75 mole percent, based on the total silver halide forming said composite crystals.
A photographic gelatino-silver halide emulsion incorporating as a discrete phase, monodispersed radiation-sensitive composite silver halide crystals comprised of
- beta-phase truncated bipyramid silver iodide crystals having a minimum mean diameter of at least about 0.2 micron,
- in each composite crystal at least one silver chloride crystal forming an epitaxial junction with the silver iodide crystal,
- at least half of the facets of the silver iodide crystal being substantially free of epitaxial silver chloride and
- silver chloride being limited to from 1 to less than 50 mole percent, based on the total silver halide forming the composite silver halide crystals.
In a photographic element comprised of a support and, as a coating on the support, a radiation-sensitive emulsion layer including a photographic vehicle as a continuous phase and, as a discrete phase, radiation-sensitive silver halide crystals,
- the improvement wherein at least a portion of the radiation-sensitive silver halide crystals are composite silver halide crystals comprised of
- multi-faceted, radiation-receptive silver iodide crystals having a minimum mean diameter of at least 0.1 micron,
- silver chloride crystals forming epitaxial junctions with the silver iodide crystals,
- at least half of the facets of the silver iodide crystal being substantially free of epitaxial silver chloride, and
- silver chloride being limited to less than 75 mole percent, based on the total silver halide forming the composite crystal.
In a photographic element comprised of a support and, at least one radiation-sensitive gelatino-silver halide emulsion layer as a coating on the support,
- the improvement wherein the radiation-sensitive gelatino-silver halide emulsion layer contains monodispersed composite silver halide crystals consisting essentially of
- beta-phase truncated bipyramid silver iodide crystals having a minimum mean diameter of at least about 0.2 micron,
- in each composite crystal at least one silver chloride crystal forms an epitaxial junction with the silver iodide crystal,
- at least half of the facets of the silver iodide crystal are substantially free of epitaxial chloride and
- the silver chloride is limited to from 1 to less than 50 mole percent, based on the total silver halide forming the composite silver halide crystals.
Dependencies are inferred from the claim text.