Removal of sulfuric acid compounds
AssigneeHoechst Aktiengesellschaft
InventorsWolfgang Hesse, Kurt Hultzsch, Albert Jung, Johannes Reese
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Abstract
Sulfuric acid compounds are removed from reaction mixtures by a reaction with unsaturated terpene compounds or with polybutadiene at elevated temperatures whereby products of reduction are formed which are volatilizable at the temperature of reaction and by expelling said products of reduction from the reaction mixture. Thus a product being substantially free from a sulfur content is obtained.
Claims32
A process for removing discoloring amounts of color forming sulfur compounds from the reaction products of a reaction mixture containing a terpene reduceable acid-reacting sulfur-containing ingredient as a reagent, reaction product or catalyst, the improvement comprising (1) reacting the reactants in the reaction mixture, (2) then reacting said acid reacting sulfur containing ingredient in the reacted mixture with an amount of an olefinic unsaturated terbene which is sufficient to react with and reduce all of said acid-reacting sulfur containing ingredients and form volatilizable reduction products of all of said sulfur containing ingredients and (3) then heating and maintaining the reacted mixture until no more gaseous products are formed at a temperature between about ambient temperature and about 320.degree. C that is sufficient to substantially reduce, volatilize and remove all of said sulfur containing reduction products to thereby provide an ultimate reaction product that is free of strong discoloring amounts of said color forming sulfur compounds.
Dependencies are inferred from the claim text.