US 3,940,353 A · Pigment dispersions and lacquers containing copolymer of isobornyl methacrylate

Abstract

Low molecular weight copolymers (1) acrylic acid esters or methacrylic acid esters of alcohols such as methanol with (2) esters of bicyclic alcohols such as isobornyl alcohol and unsaturated acids such as methacrylic acid, as contrasted with high molecular weight copolymers of such monomers (1) and (2) (see U.S. Pat. No. 3,485,775) and as contrasted to other acrylic polymers, are found to be exceptional in compatibility with practically all types of polyesters and alkyds and with many other types of lacquer film-forming materials. The modifiers, particulary for alkyds, need not be selected on the basis of the oil length or solvent (aromatic or aliphatic), the modifiers being compatible with long oil alkyds, medium oil alkyds, and short oil alkyds. When small amounts of unsaturated amine-containing monomers or unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymer solutions, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints, and printing inks are examples of uses for such blends.

Claims13

Dependent claims

A lacquer of a blend of (A) a film-forming resin selected from natural oil modified alkyd resin, methacrylated alkyd resin, styrenated alkyd resin, cellulose ester resin, vinyl resin, or chlorinated rubber, with (B) an organic solvent solution of a copolymer of about 40 to 60% by weight of a compound of the formula ##SPC3##

where X is selected from the group consisting of --CH.sub.2 --, --CH(CH.sub.3)--, and --C(CH.sub.3).sub.2 --, and M is selected from the group consisting of a hydrogen atom and at least one methyl group, and 40 to 60% by weight of styrene, vinyl toluene, or at least one ester of acrylic acid or methacrylic acid and at least one aromatic, monocyclic aliphatic, or open chain aliphatic alcohol or alkoxy alcohol having from 1 to about 18 carbon atoms, said copolymer having an average molecular weight of from 1,000 to 8,500, the weight ratio of (A) to (B) being between 9:1 and 1:9.

In a method of pigmenting a lacquer, the step of grinding a pigment in an organic solvent solution of a copolymer of about 40 to 60% by weight of a compound of the formula ##SPC6##

where X is selected from the group consisting of --CH.sub.2 --, --CH(CH.sub.3)--, and --C(CH.sub.3).sub.2 --, and M is selected from the group consisting of a hydrogen atom and at least one methyl group, and 40 to 60% by weight of styrene, vinyl toluene, or at least one ester of acrylic acid or methacrylic acid and at least one aromatic, monocyclic aliphatic, or open chain aliphatic alcohol or alkoxy alcohol having from 1 to about 18 carbon atoms, said copolymer having an average molecular weight of from 1,000 to 8,500, and blending the composition with a compatible film-forming resin.

Dependencies are inferred from the claim text.

Pigment dispersions and lacquers containing copolymer of isobornyl methacrylate

Life of this patent

Pigment dispersions and lacquers containing copolymer of isobornyl methacrylate

Life of this patent

Abstract

Claims13