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US 2026/0250429 A1Published application
Method for Producing Copolymer Having Improved Oil Retainability
AssigneeKuraray Co., Ltd.
InventorsShinya Oshita, Heith Foster
Life of this patent
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Abstract
The present invention relates to a method for producing a copolymer containing polymerizing monomers including 1,3-diene structure having 4 to 20 carbons in a solvent in a presence of an anionic polymerization initiator.
Claims28
1:
- A method for producing a copolymer, comprising:
- polymerizing monomers including 1,3-diene structure and having 4 to 20 carbons in a solvent in a presence of an anionic polymerization initiator to produce a copolymer,
- wherein a temperature change during the polymerizing is less than 15° C.
2:
- A method for producing a copolymer, comprising:
- polymerizing monomers including 1,3-diene structure and having 4 to 20 carbons in a solvent in a presence of an anionic polymerization initiator;
- and
- cooling a temperature during the polymerizing so that a consistency of the copolymer is 6 mol % or less.
1 more element
3:
- The method for producing according to claim 2,
- wherein the cooling comprises maintaining a temperature change during the polymerizing to be less than 15° C.
4:
- The method for producing according to claim 1,
- wherein a starting temperature of the polymerizing is from 10 to 90° C.
5:
- The method for producing according to claim 1,
- wherein the monomers include butadiene.
6:
- The method for producing according to claim 1,
- wherein the monomers include isoprene.
7:
- The method for producing according to claim 1,
- wherein the monomers include 7,11-dimethyl-3-methylene-1,6,10-dodecatriene (β-farnesene).
8-10. (canceled)
11:
- The method for producing according to claim 1, further comprising hydrogenating the copolymer, thereby producing a α-olefin random copolymer.
(canceled)
13:
- The method for producing according to claim 1,
- wherein the copolymer has a weight-average molecular weight from 10,000 to 500,000 Da.
14:
- The method according to claim 1,
- wherein the copolymer contains a content of 5 to 85 mol % of the vinyl bond structural unit of monomer units to a total molar amount of conjugated diene (1,3-diene structure) monomer units incorporated in the bonding mode of 3,4-, 1,4-, and 1,2-bonds of a conjugated diene monomer.
15:
- A method for producing a block copolymer, the method comprising:
- polymerizing first aromatic vinyl compounds to produce first polymerized aromatic vinyl compounds;
- and
- producing the copolymer according to the method of claim 1, thereby producing the block copolymer containing the polymerized first aromatic vinyl compounds and the copolymer,
- wherein the solvent contains the polymerized first aromatic vinyl compounds.
2 more elements
(canceled)
17:
- A method for producing a tri-block copolymer comprising:
- producing the block copolymer according to the method of claim 15;
- and
- continuously polymerizing second aromatic vinyl compounds after the block copolymer is obtained, thereby producing the tri-block copolymer comprising the polymerized first aromatic vinyl compounds, the copolymer, and the polymerized second aromatic vinyl compounds.
1 more element
18:
- The method for producing according to claim 15,
- wherein the first and second aromatic vinyl compounds each independently comprise a compound selected from the group consisting of styrene, α-methylstyrene, 4-methylstyrene, o-methylstyrene, m-methylstyrene, β-methylstyrene, 2,6-dimethylstyrene, 2,4-dimethylstyrene, α-methyl-o-methylstyrene, α-methyl-m-methylstyrene, α-methyl-p-methylstyrene, β-methyl-o-methylstyrene, β-methyl-m-methylstyrene, β-methyl-p-methylstyrene, 2,4,6-trimethylstyrene, α-methyl-2,6-dimethylstyrene, α-methyl-2,4-dimethylstyrene, 3-methyl-2,6-dimethylstyrene, f-methyl-2,4-dimethylstyrene, o-chlorostyrene, m-chlorostyrene, p-chlorostyrene, 2,6-dichlorostyrene, 2,4-dichlorostyrene, α-chloro-o-chlorostyrene, α-chloro-m-chlorostyrene, α-chloro-p-chlorostyrene, β-chloro-o-chlorostyrene, β-chloro-m-chlorostyrene, β-chloro-p-chlorostyrene, 2,4,6-trichlorostyrene, α-chloro-2,6-dichlorostyrene, α-chloro-2,4-dichlorostyrene, β-chloro-2,6-dichlorostyrene, β-chloro-2,4-dichlorostyrene, o-t-butylstyrene, m-t-butylstyrene, p-butylstyrene, o-methoxystyrene, m-methoxystyrene, p-methoxystyrene, o-chloromethylstyrene, m-chloromethylstyrene, p-chloromethylstyrene, o-bromomethylstyrene, m-bromomethylstyrene, p-bromomethylstyrene, silyl group-substituted styrene derivatives, indene, and vinylnaphthalene.
19-21. (canceled)
22:
- The method for producing according to claim 17,
- wherein the tri-block copolymer is a hydrogenated tri-block copolymer, and
- wherein a crystallization peak temperature (Tc) measured by DSC at 10° C./min of the hydrogenated tri-block copolymer is −8° C. to 4° C.
(canceled)
24:
- The method for producing according to claim 1,
- wherein the anionic polymerization initiator comprises at least one initiator selected from the group consisting of alkali metals;
- alkaline earth metals;
- lanthanoid rare earth metals;
- and compounds containing earth metals and lanthanoid rare earth metals.
2 more elements
25-31. (canceled)
32:
- The method for producing according to claim 1,
- wherein the solvent comprises at least one selected from the group consisting of saturated aliphatic hydrocarbons, saturated alicyclic hydrocarbons, and aromatic hydrocarbons.
33-38. (canceled)
39:
- The method for producing according to claim 1, further comprising adding a polymerization terminator to the solvent.
(canceled)
41:
- The method for producing according to claim 17, further comprising precipitating the tri-block copolymer in another solvent.
42:
- The method for producing according to claim 1, further comprising:
- washing the polymerization reaction liquid with water, separating, and drying.
43:
- A tri-block copolymer produced by the method of claim 17.
Dependencies are inferred from the claim text.