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US 2026/0241652 A1Published application
Process for making recyclable copolyesters articles with living hinges
AssigneeEastman Chemical Company
InventorsMarc Alan Strand, Matthew Clement Storey, Aaron David Grills, Mark Allen Peters
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Abstract
A process for making a fully recyclable packaging article comprising (1) a reclosable lid with a living hinge which comprises a copolyester composition that is recyclable in a PET stream, (2) a container which comprises a copolyester composition that is recyclable in a PET stream; and affixed thereto is (3) a crystallizable shrinkable film or label which comprises a copolyester composition that is recyclable in a PET stream.
Claims18
A process for producing a recyclable article comprising
- A) producing component A—a reclosable lid with a living hinge as a single component by injection molding at least one polyester using a mold with one or more injection points wherein the average polyester flow length divided by the average thickness of the lid is below 200;
- wherein at least one polyester comprises:
- (a) a dicarboxylic acid component comprising:
- (i) 88 to 100 mole % of terephthalic acid residues;
- (ii) 0 to 12 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms;
- and
- (b) a glycol component comprising:
- (i) 88 to 100 mole % of ethylene glycol residues;
- and
- (ii) 0 to 12 mole % of 1,4-cyclohexanedimethanol residues;
- wherein the total mole % of the acid residues is 100 mole %, and the total mole % of the glycol residues is 100 mole %;
- wherein the inherent viscosity (IhV) of said polyester ranges from 0.60 to 1.1 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.;
- and
- wherein the melting point temperature (Tm) of said polyester ranges from 225 to 255° C. as determined by ASTM D3418 at a scan rate of 10° C./min;
- B) producing component B—a container by injection stretch blow molding at least one polyester;
- wherein at least one polyester comprises:
- (a) a dicarboxylic acid component comprising:
- (i) 88 to 100 mole % of terephthalic acid residues;
- (ii) 0 to 12 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms;
- and
- (b) a glycol component comprising:
- (i) 88 to 100 mole % of ethylene glycol residues;
- and
- (ii) 0 to 12 mole % of 1,4-cyclohexanedimethanol residues;
- and
- (c) optionally at least one branching agent in the amount ranging from 0.1 to 1.0 mole % based on the total moles of glycol residues if said branching agent has hydroxyl substituents and otherwise based on the total moles of acid residues;
- wherein the total mole % of the acid residues is 100 mole %, and the total mole % of the glycol residues is 100 mole %;
- wherein the inherent viscosity (IhV) of said polyester ranges from 0.60 to 1.1 dl/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.;
- and wherein the melting point temperature (Tm) of said polyester ranges from 225 to 255° C. as determined by ASTM D3418 at a scan rate of 10° C./min.
26 more elements
Dependencies are inferred from the claim text.