Fluorinated polyaromatics with linear, branched or crosslinked structure for anion exchange membranes and ionomers

A fluorinated polyaromatic polymer comprising

• at least one fluorinated unit FU of formula I
• wherein
• X is C or N,
• Y is C,
• R1, R2, R5 and R6 are independently selected from
• H,
• —C1-C10 alkyl, wherein the —C1-C10 alkyl is substituted or unsubstituted, particularly —C1-C6 alkyl,
• —C2-C10 alkenyl, wherein the —C2-C10 alkenyl is substituted or unsubstituted, particularly —C2-C6 alkenyl,
• —C2-C10 alkynyl, wherein the —C2-C10 alkynyl is substituted or unsubstituted, particularly C2-C6 alkynyl,
• wherein at least one of R1, R2, R5 and R6 is
• Ra3, Rb4 and Rd7 are independently selected from
• —C1-C10 alkyl, wherein the —C1-C10 alkyl is substituted or unsubstituted, particularly —C1-C6 alkyl,
• —C2-C10 alkenyl, wherein the —C2-C10 alkenyl is substituted or unsubstituted, particularly —C2-C6 alkenyl,
• —C2-C10 alkynyl, wherein the —C2-C10 alkynyl is substituted or unsubstituted, particularly C2-C6 alkynyl,
• a and b are independently 0, 1, 2, or 3, particularly 0 or 1, more particularly 0,
• d is 0, 1, 2, 3 or 4, particularly 0 or 1, more particularly 0,
• n is 0 or 1,
• r is, 1, 2, 3, 4, 5 or 6, particularly, 1, 2, or 3, more particularly 1 or 2,
• p is independently between 1 and 20, particularly 1 and 15, more particularly 1 and 9, and
• q is independently between 0 and 20, particularly 0 and 15, more particularly 0 and 9,
• and
• at least one cationic unit CU of formula B or C
• wherein
• R8 is a partially or fully fluorinated C1-C6 alkyl, particularly CF3,
• R9 is selected from
• —C1-C10 alkyl, wherein the —C1-C10 alkyl is substituted or unsubstituted, particularly —C1-C6 alkyl,
• —C2-C10 alkenyl, wherein the —C2-C10 alkenyl is substituted or unsubstituted, particularly —C2-C6 alkenyl,
• —C2-C10 alkynyl, wherein the —C2-C10 alkynyl is substituted or unsubstituted, particularly C2-C6 alkynyl,
• —(CH2)s—N(R12)2,
• —(CH2)s—NHR12,
• —(CH2)s—N+(R12)3,
• wherein R12 is independently selected from
• —C1-C10 alkyl, wherein the —C1-C10 alkyl is substituted or unsubstituted, particularly —C1-C6 alkyl,
• —C2-C10 alkenyl, wherein the —C2-C10 alkenyl substituted or unsubstituted, particularly —C2-C6 alkenyl,
• —C2-C10 alkynyl, wherein the —C2-C10 alkynyl is substituted or unsubstituted, particularly C2-C6 alkynyl,
• s is between 0 and 20
• -Ph-Rf13,
• R10 and R11 are independently selected from
• H
• —C1-C10 alkyl, wherein the —C1-C10 alkyl is substituted or unsubstituted, particularly —C1-C6 alkyl,
• —C2-C10 alkenyl, wherein the —C2-C10 alkenyl is substituted or unsubstituted, particularly —C2-C6 alkenyl,
• —C2-C10 alkynyl, wherein the —C2-C10 alkynyl is substituted or unsubstituted, particularly C2-C6 alkynyl,
• or R10 and R11 are connected to each other to form a cycloalkyl comprising 4 to 10 C atoms,
• z is 0 or 1,
• A− is an anion.