Vanadium catalyst composition and preparation method and application thereof
AssigneeQingdao University of Science and Technology
InventorsLihua Na, Xuequan Zhang, Mingzhe Han, Chunyu Zhang, Heng Liu
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AssigneeQingdao University of Science and Technology
InventorsLihua Na, Xuequan Zhang, Mingzhe Han, Chunyu Zhang, Heng Liu
Estimating the term…
A vanadium catalyst composition and a preparation method and application thereof. The vanadium catalyst composition is composed of a vanadium complex and an electron donor, the ligand of the vanadium complex is one of fatty alcohols, amines and phosphate esters, the electron donor is a sulfoxide compound, and the structural formula is R—S(═O)—R′, R is selected from one of C1-C3 alkyl, aryl, C1-C3 alkyl substituted aryl; R′ is selected from one of C1-C3 alky, aromatic alkyl. An electronic donor with oxidation property is adopted, an aqueous phase extraction method is combined, and a vanadium catalyst composition with a reactivation function is synthesized by a one-step method.
A vanadium catalyst composition, comprising a vanadium complex and an electron donor, wherein the ligand of the vanadium complex is one of fatty alcohols, amines, and phosphate esters, and the structural formula of the electron donor is as shown in Formula (I):
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