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US 2026/0071125 A1Published application
Liquid crystal composition, benzoquinone derivative, liquid crystal cured layer, optical film, polarizing plate, and image display device
AssigneeFUJIFILM Corporation
InventorsHiroshi INADA, Ryoji GOTO
Life of this patent
Estimating the term…
Abstract
An object of the present invention is to provide a liquid crystal composition with which a liquid crystal cured layer having both favorable aligning properties and favorable light resistance can be produced; and to provide a benzoquinone derivative, a liquid crystal cured layer, an optical film, a polarizing plate, and an image display device. The liquid crystal composition of the present invention is a liquid crystal composition containing a compound represented by Formula (A) and a liquid crystal compound.
Claims20
A liquid crystal composition comprising:
- a compound represented by Formula (A);
- and
- a liquid crystal compound,
- in Formula (A),
- Ar1 represents any aromatic ring selected from the group consisting of groups represented by Formulae (BQ-1) to (BQ-5),
- in Formulae (BQ-1) to (BQ-5),
- * represents a bonding position to an oxygen atom,
- Q1 represents N or CH,
- Q2 represents —S—, —O—, or —N(R6)—, where R6 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- Y1 represents an aromatic hydrocarbon group having 6 to 12 carbon atoms, which may have a substituent, an aromatic heterocyclic group having 3 to 12 carbon atoms, which may have a substituent, or an alicyclic hydrocarbon group having 6 to 20 carbon atoms, which may have a substituent, where one or more of —CH2—'s constituting the alicyclic hydrocarbon group may be replaced with —O—, —S—, or —NH—,
- Z1, Z2, and Z3 each independently represent a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, a monovalent alicyclic hydrocarbon group having 3 to 20 carbon atoms, a monovalent aromatic hydrocarbon group having 6 to 20 carbon atoms, a monovalent aromatic heterocyclic group having 6 to 20 carbon atoms, a halogen atom, a cyano group, a nitro group, —OR7, —NR8R9, —SR10, —COOR11, or —COR12, where R7 to R12 each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms and Z1 and Z2 may be bonded to each other to form an aromatic ring,
- A3 and A4 each independently represent a group selected from the group consisting of —O—, —N(R13)—, —S—, and —CO—, where R13 represents a hydrogen atom or a substituent,
- X represents a non-metal atom of Groups 14 to 16, provided that a hydrogen atom or a substituent may be bonded to the non-metal atom,
- D7 and D8 each independently represent a single bond, —CO—, —O—, —S—, —C(═S)—, —CR1R2—, —CR3═CR4—, —NR5—, or a divalent linking group consisting of a combination of two or more of these groups, where R1 to R5 each independently represent a hydrogen atom, a fluorine atom, or an alkyl group having 1 to 12 carbon atoms,
- SP3 and SP4 each independently represent a single bond or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, provided that one or more of —CH2—'s constituting the aliphatic hydrocarbon group may be replaced with —O—, —S—, —NH—, —N(Q)-, or —CO—, where Q represents a substituent, and
- L3 and L4 each independently represent a monovalent organic group.
- Ax represents an organic group having 2 to 30 carbon atoms, which has at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring,
- Ay represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may have a substituent, or an organic group having 2 to 30 carbon atoms, which has at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring,
- where the aromatic rings in Ax and Ay may have a substituent, and Ax and Ay may be bonded to each other to form a ring, and
- Q3 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, which may have a substituent.
17 more elements
A benzoquinone derivative represented by Formula (A),
- in Formula (A),
- Ar1 represents any aromatic ring selected from the group consisting of groups represented by Formulae (BQ-1) to (BQ-5),
- in Formulae (BQ-1) to (BQ-5),
- * represents a bonding position to an oxygen atom,
- Q1 represents N or CH,
- Q2 represents —S—, —O—, or —N(R6)—, where R6 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms,
- Y1 represents an aromatic hydrocarbon group having 6 to 12 carbon atoms, which may have a substituent, an aromatic heterocyclic group having 3 to 12 carbon atoms, which may have a substituent, or an alicyclic hydrocarbon group having 6 to 20 carbon atoms, which may have a substituent, where one or more of —CH2—'s constituting the alicyclic hydrocarbon group may be replaced with —O—, —S—, or —NH—,
- Z1, Z2, and Z3 each independently represent a hydrogen atom, a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, a monovalent alicyclic hydrocarbon group having 3 to 20 carbon atoms, a monovalent aromatic hydrocarbon group having 6 to 20 carbon atoms, a monovalent aromatic heterocyclic group having 6 to 20 carbon atoms, a halogen atom, a cyano group, a nitro group, —OR7, —NR8R9, —SR10, —COOR11, or —COR12, where R7 to R12 each independently represent a hydrogen atom or an alkyl group having 1 to 6 carbon atoms and Z1 and Z2 may be bonded to each other to form an aromatic ring,
- A3 and A4 each independently represent a group selected from the group consisting of —O—, —N(R13)—, —S—, and —CO—, where R13 represents a hydrogen atom or a substituent,
- X represents a non-metal atom of Groups 14 to 16, provided that a hydrogen atom or a substituent may be bonded to the non-metal atom,
- D7 and D8 each independently represent a single bond, —CO—, —O—, —S—, —C(═S)—, —CR1R2—, —CR3═CR4—, —NR5—, or a divalent linking group consisting of a combination of two or more of these groups, where R1 to R5 each independently represent a hydrogen atom, a fluorine atom, or an alkyl group having 1 to 12 carbon atoms,
- SP3 and SP4 each independently represent a single bond or a divalent aliphatic hydrocarbon group having 1 to 20 carbon atoms, provided that one or more of —CH2—'s constituting the aliphatic hydrocarbon group may be replaced with —O—, —S—, —NH—, —N(Q)-, or —CO—, where Q represents a substituent, and
- L3 and L4 each independently represent a monovalent organic group.
- Ax represents an organic group having 2 to 30 carbon atoms, which has at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring,
- Ay represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, which may have a substituent, or an organic group having 2 to 30 carbon atoms, which has at least one aromatic ring selected from the group consisting of an aromatic hydrocarbon ring and an aromatic heterocyclic ring,
- where the aromatic rings in Ax and Ay may have a substituent, and Ax and Ay may be bonded to each other to form a ring, and
- Q3 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, which may have a substituent.
14 more elements
Dependencies are inferred from the claim text.