Hyper-cross-linked polyamide/polyamine 3d-network for water treatment

2:

• The polymeric adsorbent of claim 1, wherein one or more primary amines and one or more secondary amines of the reacted units of the TEPA are covalently bonded to the reacted units of the 3,5-diacrylamidobenzoic acid through one or more primary carbons of the reacted units of the 3,5-diacrylamidobenzoic acid.

3:

• The polymeric adsorbent of claim 1, wherein one or more primary amines and one or more secondary amines of the reacted units of the TEPA are covalently bonded to the reacted units of the methacrylamide through one or more primary carbons of the reacted units of the methacrylamide.

5:

• The polymeric adsorbent of claim 1, wherein the adsorbent is in the form of agglomerates having a longest dimension of 5 to 50 μm made of particles having an average particle size of 25 to 250 nm and a surface area of 5 to 15 meter square per gram (m2/g).

6:

• The polymeric adsorbent of claim 1, wherein the adsorbent is in the form of particles that are porous and have a pore volume of 0.01 to 0.1 cubic centimeters per gram (cm3/g).

7:

• The polymeric adsorbent of claim 1, wherein the adsorbent is in the form of particles that are porous and have a pore size of 1 to 3 nanometers (nm).

8:

• The polymeric adsorbent of claim 1, wherein the adsorbent is in the form of particles that are agglomerated and have an average particle size of 50 to 300 nm.

10:

• The method of claim 9, wherein the one or more pollutants are one or more metal ions and the one or more metal ions are adsorbed onto the polymeric adsorbent through metal ligand complexation with one or more amines of the reacted units of the TEPA and the reacted units of the methacrylamide.

11:

• The method of claim 9, wherein the one or more pollutants are one or more metal ions and the one or more metal ions are adsorbed onto the polymeric adsorbent through electrostatic interactions with one or more oxygen-containing functional groups of the reacted units of the 3,5-diacrylamidobenzoic acid and the reacted units of the methacrylamide.

13:

• The method of claim 12, wherein the regenerated polymeric adsorbent has a removal efficiency of the one or more pollutants of at least 50 percent (%) based on an initial amount of the one or more pollutants in the aqueous solution.

14:

• The method of claim 12, wherein adsorption of the one or more pollutants occurs in less than 10 minutes.

15:

• The polymeric adsorbent of claim 1, wherein the adsorbent has an adsorption capacity of 58 to 64 milligrams per gram (mg/g) for cadmium ions.

16:

• The polymeric adsorbent of claim 1, wherein the adsorbent has an adsorption capacity of 116 to 122 mg/g for chromium ions.

17:

• The polymeric adsorbent of claim 1, wherein the adsorbent has an adsorption capacity of 5 to 15 mg/g for lead ions.

18:

• The polymeric adsorbent of claim 1, wherein the adsorbent has a dye removal efficiency for eriochrome black t (EBT) of at least 99% based on an initial amount of the eriochrome black t.

19:

• The polymeric adsorbent of claim 1, wherein the adsorbent has a dye removal efficiency for methyl orange (MO) of 35 to 45% based on an initial amount of the MO.

20:

• The polymeric adsorbent of claim 1, wherein carboxylic acid functional groups in the reacted units of the 3,5-diacrylamidobenzoic acid do not react with reacted units of the TEPA and reacted units of the TEPA.