Method for recovering lithium from waste lithium ion batteries

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution A to extract and separate manganese and also to obtain a solution B;
• a cobalt extraction step of adding an organophosphorus compound extraction solvent to the solution B to extract and separate cobalt and also to obtain a solution C;
• a nickel extraction step of adding an organophosphorus compound extraction solvent to the solution C to extract and separate nickel and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the manganese extraction step, the cobalt extraction step, and the nickel extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution A to extract and separate manganese and also to obtain a solution D;
• a nickel extraction step of adding a hydroxime extraction solvent to the solution D to extract and separate nickel and also to obtain a solution E;
• a cobalt extraction step of adding an organophosphorus compound extraction solvent to the solution E to extract and separate cobalt and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the manganese extraction step, the nickel extraction step, and the cobalt extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a cobalt extraction step of adding an organic amine compound extraction solvent to the solution A to extract and separate cobalt and also to obtain a solution F;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution F to extract and separate manganese and also to obtain a solution G;
• a nickel extraction step of adding an organophosphorus compound extraction solvent to the solution G to extract and separate nickel and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the cobalt extraction step, the manganese extraction step, and the nickel extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a cobalt extraction step of adding an organic amine compound extraction solvent to the solution A to extract and separate cobalt and also to obtain a solution H;
• a nickel extraction step of adding a hydroxime extraction solvent to the solution H to extract and separate nickel and also to obtain a solution I;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution I to extract and separate manganese and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the cobalt extraction step, the nickel extraction step, and the manganese extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a nickel extraction step of adding a hydroxime extraction solvent to the solution A to extract and separate nickel and also to obtain a solution J;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution J to extract and separate manganese and also to obtain a solution K;
• a cobalt extraction step of adding an organophosphorus compound extraction solvent to the solution K to extract and separate cobalt and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the nickel extraction step, the manganese extraction step, and the cobalt extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization and solid-liquid separation step of solid-liquid separating the solution into insoluble matters and a solution A produced by neutralization with lithium hydroxide;
• a nickel extraction step of adding a hydroxime extraction solvent to the solution A to extract and separate nickel and also to obtain a solution L;
• a cobalt extraction step of adding an organic amine compound extraction solvent to the solution L to extract and separate cobalt and also to obtain a solution M;
• a manganese extraction step of adding an organophosphorus compound extraction solvent to the solution M to extract and separate manganese and also to obtain a first lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization and solid-liquid separation step, the nickel extraction step, the cobalt extraction step, and the manganese extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization step of neutralizing the solution with lithium hydroxide;
• a solvent extraction step of separating at least one metal excluding lithium, out of metals contained in the active material powder, from the acid solution to which lithium hydroxide has been added by organic solvent extraction to obtain a first lithium salt aqueous solution as a residual liquid of the solvent extraction;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization step and the solvent extraction step,
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step, and
• the organic solvent is at least one selected from a group consisting of an organophosphorus compound, a hydroxime, and an organic amine compound.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization step of neutralizing the solution with lithium hydroxide;
• a solvent extraction step of separating at least one metal excluding lithium, out of metals contained in the active material powder, from the acid solution to which lithium hydroxide has been added by solvent extraction to obtain a first lithium salt aqueous solution as a residual liquid of the solvent extraction;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization step and the solvent extraction step,
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step, and
• in the solvent extraction step, an alkali-containing organic solvent obtained by mixing an alkali aqueous solution and the organic solvent, followed by oil-water separation, is mixed with the acid solution.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization step of neutralizing the solution with lithium hydroxide;
• a metal sulfide removal step of mixing the acid solution to which lithium hydroxide has been added with a sulfide in a pH range of 2 to 6 to produce a sulfide of at least one metal selected from a group consisting of copper, cadmium, lead, and mercury, and removing the metal sulfide;
• a solvent extraction step of separating at least one metal excluding lithium, out of metals contained in the active material powder, from the acid solution from which the metal sulfide has been removed by solvent extraction to obtain a first lithium salt aqueous solution as a residual liquid of the solvent extraction;
• and
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization step and the solvent extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization step of neutralizing the solution with lithium hydroxide;
• a solvent extraction step of separating at least one metal excluding lithium, out of metals contained in the active material powder, from the acid solution to which lithium hydroxide has been added by solvent extraction to obtain a first lithium salt aqueous solution as a residual liquid of the solvent extraction;
• a membrane electrolysis step of subjecting the first lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a second lithium salt aqueous solution that is more dilute than the first lithium salt aqueous solution;
• and
• a carbonation step of carbonating the lithium hydroxide aqueous solution and the second lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization step and the solvent extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.

A method for recovering lithium from waste lithium ion batteries, the method comprising:

• a dissolution step of dissolving active material powder obtained by pre-processing the waste lithium ion batteries in a mineral acid to obtain a solution;
• a neutralization step of neutralizing the solution with lithium hydroxide;
• a solvent extraction step of separating at least one metal excluding lithium, out of metals contained in the active material powder, from the acid solution to which lithium hydroxide has been added by solvent extraction to obtain a first lithium salt aqueous solution as a residual liquid of the solvent extraction;
• a nickel removal step of mixing the first lithium salt aqueous solution and an alkali to remove nickel contained in the first lithium salt aqueous solution and to obtain a second lithium salt aqueous solution;
• and
• a membrane electrolysis step of subjecting the second lithium salt aqueous solution to membrane electrolysis using an ion exchange membrane to obtain a lithium hydroxide aqueous solution, an acid, and a third lithium salt aqueous solution that is more dilute than the second lithium salt aqueous solution,
• wherein the lithium hydroxide aqueous solution obtained in the membrane electrolysis step is reused in at least one selected from a group consisting of the neutralization step and the solvent extraction step, and
• the acid obtained in the membrane electrolysis step is reused as the mineral acid used in the dissolution step.