Domain wall straightening method of periodically poled ferroelectric crystal

A domain wall straightening method of a periodically poled ferroelectric crystal, comprising the following steps:

• step 1:
• making a negative polarity surface of a sample to be poled upward by a quasi-static test method, with a piezoelectric coefficient of ds, and ds>0, and then periodically poling the sample;
• placing one surface of the poled sample on an insulating plate for testing a piezoelectric coefficient dc, and then placing the sample on the insulating plate in reverse for testing a piezoelectric coefficient dr;
• when the absolute values of dc and dr are both greater than ds/2, continuing to pole the sample;
• when the absolute value of the tested piezoelectric coefficient is less than ds/2, if a difference in the absolute values of dc and dr is less than 20%, judging that a poled reversed domain penetrates through the entire crystal, and obtaining a domain penetrated crystal for use;
• if the difference in the absolute values of dc and dr is greater than 20%, judging that the reversed domain does not penetrate through the entire crystal, stopping the poling, conducting single domain for the sample, and conducting periodic poling again;
• step 2:
• placing the domain penetrated crystal in step 1 upward in the original negative polarity direction instead of on the insulating plate by the quasi-static test method, and testing a piezoelectric coefficient dp;
• step 3:
• calculating the duty cycle of a test region by a formula D=(dp+ds)/2ds;
• wherein if dp>0, the duty cycle of the reversed domain is 1−D, which indicates that the area of the reversed domain region is smaller than the area of an unreversed domain region, and if dp<0, the duty cycle of the reversed domain is D, which indicates that the area of the reversed domain region is larger than the area of the unreversed domain region;
• step 4:
• selecting multiple points on the poled sample for testing the piezoelectric coefficient, and calculating the duty cycle distribution condition of different regions of the poled sample according to step 3;
• step 5:
• according to the results obtained from step 3, if the duty cycle D is greater than a designed duty cycle by 20%, conducting single domain for the sample and conducting periodic poling again;
• and if the duty cycle D is greater than 0 but less than 20% than the designed duty cycle, continuing to pole the sample, and adjusting the size of poling voltage according to the change quantity Δdp of the piezoelectric coefficient dp;
• step 6:
• testing equidistant regions on a same coordinate axis;
• if 2% ds≥Δdp≥0.5% ds in any region, indicating that the transverse growth rate of reversal is in a reasonable range, and indicating that the domain wall tends to be flat;
• and according to step 5, judging whether to continue poling, and finally making the duty cycle D and the designed duty cycle reach an error range of ±0.5%;
• if Δdp>2% ds in any region, reducing the voltage;
• taking out the sample after poling for testing the piezoelectric coefficient;
• and repeating the above calculation to judge whether to continue the poling until the duty cycle reaches 50%;
• if Δdp<0.5% ds in any region, increasing the voltage;
• taking out the sample after poling for testing the piezoelectric coefficient;
• and repeating the above calculation to judge whether to continue the poling until the duty cycle reaches 50%.