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US 2025/0145772 A1Published application
Crosslinked copolymer, polymer membrane comprising the same, and anion exchange membrane comprising the polymer membrane
AssigneeHanwha Solutions Corporation
InventorsTae-Hyun KIM, Kyungwhan MIN, Yerim LEE
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Abstract
A novel cross-linked copolymer is disclosed. The novel cross-linked copolymer can be preferably used as an anion exchange membrane (AEM) material for fuel cells because of its excellent mechanical properties, excellent stability against hydroxide ions, and high ion conductivity and hydration.
Claims13
1:
- A crosslinked copolymer comprising a first chain represented by the following Chemical Formula 1 and a second chain represented by the following Chemical Formula 2, wherein the first chain and the second chain are crosslinked with each other:
- in Chemical Formula 1,
- * is a bonding position with Chemical Formula 2,
- a sum of q1, q2, q5, and q6 is an integer of 100 to 1,000,
- a sum of q3 and q4 is an integer of 150 to 2,000,
- a and b are each independently an integer of 3 to 10, and
- R1 to R4 are each independently hydrogen or —(CH2)p—CH3, wherein p is an integer of 0 to 5,
- in Chemical Formula 2,
- * is a bonding position with Chemical Formula 1,
- R5 is —(CH2)p′—CH3, wherein p′ is an integer of 0 to 5, and
- n is an integer of 10 to 1000.
8 more elements
2:
- The crosslinked copolymer of claim 1,
- wherein 10 to 70 mol of the second chain is included based on 100 mol of the first chain.
3:
- The crosslinked copolymer of claim 1,
- wherein q1 to q6 are each independently an integer of 10 to 500.
4:
- The crosslinked copolymer of claim 1,
- wherein a ratio of the sum of q1, q2, q5, and q6 to the sum of q1 to q6 is 0.2 to 0.5.
5:
- The crosslinked copolymer of claim 1,
- wherein a ratio of the sum of q1 to q6 to the sum of q1, q2, q5, and q6 is 0.2 to 0.5.
6:
- The crosslinked copolymer of claim 1,
- wherein a and b are each independently an integer of 4 to 6.
7:
- The crosslinked copolymer of claim 1,
- wherein the crosslinked copolymer is represented by the following Chemical Formula 3:
- in Chemical Formula 3, q1 to q6, a, b, and n are as defined in the Chemical Formulae 1 and 2.
8:
- A polymer membrane comprising the crosslinked copolymer of claim 1.
9:
- The polymer membrane of claim 8,
- wherein the polymer membrane is an anion exchange membrane.
10:
- A method for preparing a crosslinked copolymer comprising the steps of
- (a) preparing a poly(styrene-b-ethylene-co-butylene-b-styrene)-based polymer represented by the following Chemical Formula 1-1;
- (b) preparing a poly(m-terphenyl N-alkyl piperidine) polymer represented by the following Chemical Formula 2-1;
- and
- (c) preparing a crosslinked copolymer by crosslinking the poly(styrene-b-ethylene-co-butylene-b-styrene)-based polymer and the poly(m-terphenyl N-methyl piperidine) polymer:
- in Chemical Formula 1-1,
- a sum of q1, q2, q5, and q6 is an integer of 100 to 1,000,
- a sum of q3 and q4 is an integer of 150 to 2,000,
- a and b are each independently an integer of 3 to 10, and
- R1 to R4 are each independently hydrogen or —(CH2)p—CH3, wherein p is an integer of 0 to 5, and
- X1 and X2 are each independently a halogen group,
- in Chemical Formula 2-1,
- R5 is —(CH2)p′—CH3, wherein p′ is an integer of 0 to 5, and
- n is an integer of 10 to 1000.
11 more elements
11:
- The method for preparing a crosslinked copolymer of claim 10,
- further comprising a step (d) of reacting the crosslinked copolymer with trimethylamine.
12:
- The method for preparing a crosslinked copolymer of claim 10,
- wherein the poly(styrene-b-ethylene-co-butylene-b-styrene)-based polymer contains 30 to 90 mol of halogen groups based on 100 mol of styrene repeating units.
13:
- The method for preparing a crosslinked copolymer of claim 10,
- wherein the poly(m-terphenyl N-alkyl piperidine) polymer is used in an amount of 10 to 70 mol based on 100 mol of the halogen groups contained in the poly(styrene-b-ethylene-co-butylene-b-styrene)-based polymer in the step (c).