Anion exchange resin, anion exchange membrane, anion-exchange-group-containing monomer, and quaternary-imidazole-group-containing monomer
AssigneesKake Educational Institution, Tokuyama Corporation
InventorsHideyuki HIGASHIMURA, Md Chanmiya SHEIKH, Takenori ISOMURA, Masahiro UWAMORI
Life of this patent
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Abstract
To provide an anion exchange resin which has an anion exchange group having high alkali resistance and in which a main chain structure is not affected even if the anion exchange group decomposes. The anion exchange resin according to the present invention is characterized by having an imidazolium group as an anion exchange group in a side chain.
Claims17
An anion exchange resin comprising a side chain shown by a below formula (1)
- In the formula (1), R1, R2, R3, R4, R7, R8, and R9 each represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a group which bonds with a main chain forming the anion exchange resin;
- R5 and R6 each represents an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a group which bonds with the main chain forming the anion exchange resin;
- at least one of R1, R2, R3, R4, R5, R6, R7, R8, and R9 is a group which bonds with the main chain of the anion exchange resin;
- and
- Xn− represents an anion and n represents an anion valance.
An anion exchange group-containing monomer shown by a below formula (2)
- In the formula (2), R1, R2, R3, R4, R7, R8, and R9 each represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a polymerizable group shown by a below formula (P);
- R5 and R6 each represents an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a polymerizable group shown by a below formula (P);
- at least one of R1, R2, R3, R4, R5, R6, R7, R8, and R9 is the polymerizable group shown by the below formula (P);
- and
- Xn− represents an anion and n represents an anion valance
- In the formula (P), R10 and R11 each represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, or an aryl group which may contain a substituent group;
- m is an integer of 0 to 10;
- R12 represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, or an aryl group which may contain a substituent group;
- p is an integer of 0 to 4;
- and
- q is an integer of 0 to 10.
A monomer containing an imidazole group shown by a below formula (3)
- In the formula (3), R1, R2, R3, R4, R7, R8, and R9 each represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a polymerizable group shown by a below formula (P);
- R6 represents an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, an aryl group which may contain a substituent group, or a polymerizable group shown by a below formula (P);
- and
- at least one of R1, R2, R3, R4, R6, R7, R8, and R9 is a polymerizable group shown by below formula (P)
- In the formula (P), R10 and R11 each represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, or an aryl group which may contain a substituent group;
- m is an integer of 0 to 10;
- R12 represents a hydrogen atom, an alkyl group which may contain a substituent group, a cycloalkyl group which may contain a substituent group, or an aryl group which may contain a substituent group;
- p is an integer of 0 to 4;
- and
- q is an integer of 0 to 10.
Dependencies are inferred from the claim text.