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US 2025/0116934 A1Published application
Onium salt monomer, polymer, chemically amplified resist composition, and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorMasahiro Fukushima
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Abstract
An onium salt monomer containing an aromatic sulfonic acid anion having a vinyl-substituted aromatic ring is provided as well as a polymer comprising repeat units derived from the monomer. A chemically amplified resist composition comprising the polymer has advantages including high sensitivity, high contrast, improved lithography properties, e.g., EL, LWR, CDU and DOF, collapse resistance during fine pattern formation, and etch resistance after development.
Claims16
An onium salt monomer having the formula (a):
- wherein n1 is 0 or 1, n2 is 0 or 1, n3 is an integer of 0 to 4, n4 is an integer of 0 to 4, n5 is an integer of 0 to 4, n4+n5 is from 0 to 4 when n2=0, n4+n5 is from 0 to 6 when n2=1, excluding that all n1 to n5 are 0,
- RA is hydrogen, fluorine, methyl or trifluoromethyl,
- R1 is halogen or a C1-C20 hydrocarbyl group which may contain a heteroatom, a plurality of R1 may bond together to form a ring with the carbon atoms on aromatic ring to which they are attached when n3 is 2, 3 or 4,
- R2 is a C1-C20 hydrocarbyl group which may contain a heteroatom, a plurality of R2 may bond together to form a ring with the carbon atoms to which they are attached when n4 is 2, 3 or 4,
- RF is fluorine, C1-C6 fluorinated alkyl group, C1-C6 fluorinated alkoxy group, or C1-C6 fluorinated alkylthio group,
- LA and LB are each independently a single bond, ether bond, ester bond, sulfonate ester bond, sulfonic amide bond, carbonate bond or carbamate bond,
- XL is a single bond or C1-C40 hydrocarbylene group which may contain a heteroatom, and
- Z+ is an onium cation.
5 more elements
Dependencies are inferred from the claim text.