Organotin photoresist composition for photolithography patterning
OwnerFeng Luinventor
Life of this patent
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Abstract
An organotin photoresist composition for photolithography patterning is described, wherein organotin photoresist composition comprises a (cyclopentadienyl)tin compound, a solvent, and/or an additive. (Cyclopentadienyl)tin compound comprises cyclopentadienyl, or substituted cyclopentadienyl C5H4R, C5H3R2, C5H2R3, C5HR4, or C5R5 group, wherein R is H, a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group with 6-20 carbon atoms, or an amino, cyano, ether, ester, halide, nitro, silyl, thiol, or carbonyl group.
Claims18
An organotin photoresist composition for photolithography patterning, comprising:
- a (cyclopentadienyl)tin compound, a solvent, and/or an additive;
- wherein (cyclopentadienyl)tin compound is one or more selected from chemical formulas (1)-(23) as below:
- wherein R1, R2, R3 are independently —R′, -ER′, —N(R′)2, —O—(C═O)—R′, —(C═O)—R′, —N(R′)—(C═O)—R′, or —(C═O)—N(R′)2 group, wherein R′ is H, a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group with 6-20 carbon atoms;
- wherein Ra, Rb, Rc, Rd are each independently H, a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group with 6-20 carbon atoms;
- E=O, S, Se, or Te, X=F, Cl, Br, or I.
A method for photolithography patterning, comprising:
- depositing an organotin photoresist composition over a substrate;
- wherein the organotin photoresist comprises a (cyclopentadienyl)tin compound,
- wherein the (cyclopentadienyl)tin compound is one or more selected from chemical formulas (1)-(23) as below:
- wherein R1, R2, R3 are independently —R′, -ER′, —N(R′)2, —O—(C═O)—R′, —(C═O)—R′, —N(R′)—(C═O)—R′, or —(C═O)—N(R′)2 group, wherein R′ is H, a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group with 6-20 carbon atoms;
- wherein Ra, Rb, Rc, Rd are each independently H, a substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group with 6-20 carbon atoms;
- E=O, S, Se, or Te, X=F, Cl, Br, or I;
- exposing the organotin photoresist layer to actinic radiation to form a latent pattern;
- and
- developing the latent pattern by applying a developer to remove the unexposed or exposed portion of photoresists to form a photolithography pattern.
An organotin compound bearing cyclopentadienyl group represented by chemical formulas as below:
- wherein R1, R2 are independently an alkyl, alkenyl, alkynyl, cycloalkyl, or cycloalkenyl group with 1 to 20 carbon atoms, or an aryl group with 6-20 carbon atoms;
- E=O, S, Se, or Te.
Dependencies are inferred from the claim text.