Corrosion inhibition system primers and adhesives for metal bond structures

An adhesively bonded structure, comprising:

• a first substrate;
• a second substrate;
• and
• a corrosion inhibiting adhesive system disposed therebetween comprising:
• a primer layer including a functionalized nanomaterial dopant, and
• an adhesive layer disposed on the primer layer including the functionalized nanomaterial dopant,
• wherein the functionalized nanomaterial dopant comprises a nanomaterial dopant and a functionalizer, wherein the nanomaterial dopant comprises at least one of graphene nanoplatelets, carbon nanotubes, and carbon nanofibers, and wherein the functionalizer comprises at least one of an organosilane, an oxysilane, an amine, an epoxide, a mercapto group, a phosphate ester, a titanate, an aliphatic species, an aromatic species, or a compound formed via esterification.