(1,4,5-trisubstituted 1h-pyrazol-3-yl)oxy-2-alkylthioalkyl acids and -alkyl acid derivatives, salts thereof and use thereof as active herbicidal ingredients

(1,4,5-Tri substituted 1H-pyrazol-3-yl)oxy-2-alkoxythioalkyl acids, and derivatives thereof, of the general formula (I)

• and the agrochemically acceptable salts, N-oxides, hydrates and hydrates of the salts and hydrates of the N-oxides thereof, where
• A is selected from the group consisting of A1, A2 and A3
• Q is selected from the group consisting of Q1-Q16
• R1 is OR1a or NR9R10;
• R1a is hydrogen or
• is (C1-C6)-alkyl, (C3-C6)-cycloalkyl, which is unsubstituted or in each case independently substituted by “m” radicals selected from the group consisting of COOR5, halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C3-C6)-cycloalkyl, (C1-C6)-alkoxy, cyano and nitro or
• is (C3-C4)-alkenyl, (C3-C4)-alkynyl, or
• is (C1-C6)-alkyl-S—(C1-C6)-alkyl-, (C1-C6)-alkyl-SO—(C1-C6)-alkyl-, (C1-C6)-alkyl-SO2—(C1-C6)-alkyl-, or
• is heterocyclyl, heteroaryl, aryl or
• is heterocyclyl-(C1-C4)-alkyl-, heteroaryl-(C1-C4)-alkyl-, aryl-(C1-C4)-alkyl-, which is unsubstituted or in each case independently substituted by “m” radicals selected from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl;
• R9 is hydrogen, (C1-C12)-alkyl;
• R10 is hydrogen, aryl, heteroaryl, heterocyclyl, (C1-C12)-alkyl, (C3-C8)-cycloalkyl, (C3-C8)-cycloalkyl-(C1-C7)-alkyl-, (C2-C12)-alkenyl, (C5-C7)-cycloalkenyl, (C2-C12)-alkynyl, S(O)nR5, cyano, OR5, SO2NR6R7, CO2R8, COR8, where the abovementioned alkyl, cycloalkyl, alkenyl, cycloalkenyl and alkynyl radicals are unsubstituted or each independently substituted by “m” radicals selected from the group consisting of mono- or polysubstituted aryl, halogen, cyano, nitro, OR5, S(O)nR5, SO2NR6R7, CO2R8, CONR6R8, COR6, NR6R8, NR6COR8, NR6CONR8R8, NR6CO2R8, NR6SO2R8, NR6SO2NR6R8, C(R6)═NOR8;
• or
• R9 and R10 together with the nitrogen atom to which they are bonded form a saturated or partly or fully unsaturated five-, six- or seven-membered ring which is substituted by “m” radicals from the group consisting of halogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, OR5, S(O)nR5, CO2R8, CONR6R8, COR6 and C(R6)═NOR8 and which, in addition to this nitrogen atom, contains ‘r’ carbon atoms, “o” oxygen atoms, “p” sulfur atoms and “q” elements from the group consisting of NR7, CO and NCOR7 as ring atoms;
• R5 is (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-haloalkyl, aryl;
• R6 is hydrogen, (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-haloalkyl, aryl;
• R7 is hydrogen, (C1˜C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C4)-alkenyl, (C3-C4)-alkynyl;
• R8 is hydrogen, (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C3-C4)-alkenyl, (C1-C6)-alkyl-COO(C1-C2)-alkyl- or (C3-C4)-alkynyl;
• R2 is (C1-C4)-alkylthio;
• R3 is halogen, cyano, isocyano, nitro, (C1-C6)-alkyl, (C3-C6)-cycloalkyl, (C1-C6)-haloalkyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkylcarbonyl-, (C1-C6)-haloalkylcarbonyl-, (C1-C6)-alkyloxycarbonyl-, (C2-C3)-alkenyl, (C2-C3)-haloalkenyl, (C2-C3)-alkynyl, (C2-C3)-haloalkynyl, (C1-C6)-alkyl-S(O)n and (C1-C6)-haloalkyl-S(O)n, CHO and NH2;
• R12 is halogen, cyano, nitro, (C1-C6)-alkyl, (C1-C6)-haloalkyl;
• R13 is halogen, cyano, nitro, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C1-C6)-alkylcarbonyl, (C1-C6)-haloalkylcarbonyl, (C1-C6)-alkoxycarbonyl, (C1-C6)-alkoxy, (C1-C6)-haloalkoxy, (C1-C6)-alkylS(O)n, (C2-C3)-alkenyl, (C2-C3)-haloalkenyl, (C2-C3)-alkynyl, (C2-C3)-haloalkynyl;
• h is 0, 1 or 2;
• i is 0, 1, 2 or 3;
• k is 0, 1, 2, 3 or 4;
• m is 0, 1, 2 or 3;
• n is 0, 1 or 2;
• is 0, 1 or 2;
• p is 0 or 1;
• q is 0 or 1;
• r is 3, 4, 5 or 6;
• s is 0, 1, 2, 3, 4 or 5.