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US 2024/0424489 A1Published application
Pincer-based cobalt catalysts for hydrogenation reaction and its process of preparation thereof
OwnerBenudhar Punji, Dipesh Mamraj Sharmainventors
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Abstract
The present invention relates to a pincer-based cobalt catalyst of formula (I) for hydrogenation of alkynes, and its process of preparation thereof. More particularly the present invention also relates to a process for the hydrogenation of alkynes to alkenes.
Claims12
1-11. (canceled)
A pincer-based cobalt catalyst for hydrogenation of alkynes to alkenes, the pincer-based cobalt catalyst having formula (I):
- where:
- R1 is selected from the group consisting of hydrogen, C1-C5 alkyl, alkoxy, aryl, trifluoromethyl, halogen, amino, and alkylamino;
- R2 and R3 are either both hydrogen or together form a cyclic arene;
- R4 is selected from the group consisting of hydrogen and C1-C6 alkyl;
- R5 is selected from —CH2 or —C(O);
- R6 and R7 are each independently selected from the group consisting of C1-C6 alkyl and aryl;
- R8 is selected from hydrogen and cyclic arene;
- X1 and X2 are selected from the group consisting of —Cl, —Br, —I, —OTf, and —OC(O)CH3;
- n is 0, 1, or 2;
- and
- when a Co—N bond is present, a N—R8 bond is absent.
8 more elements
Dependencies are inferred from the claim text.