Oxide fluorescent material and light emitting device using the same
AssigneeNichia Corporation
InventorYoshinori MURAZAKI
Life of this patent
Estimating the term…
Abstract
An oxide fluorescent material has a composition represented by the following formula (1). (Ga1-uM1u)2(Ge1-vM2v)wOx:Cry,M3z (1), wherein M1 represents at least one element selected from the group consisting of Al, Sc, and In; M2 represents at least one element selected from the group consisting of Si, Ti, Zr, Sn, and Hf, M3 represents at least one element selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb; and u, v, w, x, y, and z satisfy 0≤u≤1.0, 0≤v≤0.5, 1.0≤w≤3.0, 5≤x≤9, 0.005≤y≤1.0, and 0≤z≤0.5, respectively.
Claims12
An oxide fluorescent material, having a composition represented by the following formula (1):
- (Ga1-uM1u)2(Ge1-vM2v)wOx:Cry,M3z (1),
- wherein M1 represents at least one element selected from the group consisting of Al, Sc, and In;
- M2 represents at least one element selected from the group consisting of Si, Ti, Zr, Sn, and Hf, M3 represents at least one element selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb;
- and u, v, w, x, y, and z satisfy 0≤u≤1.0, 0≤v≤0.5, 1.0≤w≤3.0, 5≤x≤9, 0.005≤y≤1.0, and 0≤z≤0.5, respectively.
A method for producing an oxide fluorescent material, comprising:
- adjusting and mixing a first compound containing Ga and/or a second compound containing at least one first element M1 selected from the group consisting of Al, Sc, and In, a third compound containing Ge, a fourth compound containing Cr, optionally a fifth compound containing at least one second element M2 selected from the group consisting of Si, Ti, Zr, Sn, and Hf, and optionally a sixth compound containing at least one third element M3 selected from the group consisting of Ni, Eu, Fe, Mn, Nd, Tm, Ho, Er, and Yb to provide a raw material mixture such that:
- when a total molar ratio of Ga and/or the at least one first element M1 in the composition of the oxide fluorescent material is 2, a molar ratio of the at least one first element M1 is a product of a parameter u and 2, wherein the parameter u is a numerical value of 0 or more and 1.0 or less, a molar ratio of Ga is a product of 2 and a value of 1 minus the parameter u, a molar ratio of the at least one second element M2 is a product of a parameter v and a parameter w, wherein the parameter v is a numerical value of 0 or more and 0.5 or less, wherein the parameter w is a numerical value of 1.0 or more and 3.0 or less, a molar ratio of Ge is a product of the parameter w and a value of 1 minus the parameter v, a molar ratio of Cr is the parameter y, wherein the parameter y is a numerical value of 0.005 or more and 1.0 or less, a molar ratio of the at least one third element M3 is a parameter z, wherein the parameter z is a numerical value of 0 or more and 0.5 or less;
- and
- heat-treating the raw material mixture at a temperature in a range of 800° C. or higher and 1,400° C. or lower in an atmosphere containing oxygen to obtain an oxide fluorescent material,
- wherein at least one selected from the group consisting of the first compound, the second compound, the third compound, and the fourth compound comprises an oxide.
Dependencies are inferred from the claim text.