Additive-containing biopolymer compositions
AssigneeWacker Chemie AG
InventorsOliver Fuhrmann, Manuela Lamprecht, Karl Weber, Angelika Weißenbacher
Life of this patent
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Abstract
Polymer compositions and methods for producing the same. The polymer compositions include a component (A), a component (B) and a component (C). Where the component (A) is 65% to 99.4% by weight of biopolymers, the component (B) is 0.5% to 30% by weight of homopolymers, copolymers or terpolymers based on vinyl acetate and the component (C) is 0.1% to 5% by weight of organopolysiloxane pellets.
Claims9
1-8. (canceled)
A composition, comprising:
- a component (A) that is 65% to 99.4% by weight of biopolymers selected from the group consisting of
- polylactic acid (PLA),
- polybutylene succinate (PBS),
- polybutylene succinate adipate (PBSA),
- thermoplastic starch (TPS),
- polyhydroxyalkanoate (PHA),
- polybutylene adipate terephthalate (PBAT),
- polybutylene sebacate terephthalate (PBST),
- polyhydroxybutyrate (PHB),
- polycaprolactone (PCL),
- and cellophane (CA), and
- mixtures thereof;
- a component (B) that is 0.5% to 30% by weight of homopolymers, copolymers or terpolymers based on vinyl acetate;
- and
- a component (C) that is 0.1% to 5% by weight of organopolysiloxane pellets comprising
- (1) 100 parts by weight of at least one polyorganosiloxane composed of units of general formula
- RrSiO(4-r/2) (I)
- where R is identical or different and is a substituted or unsubstituted hydrocarbon radical and r is 0, 1, 2 or 3, with the proviso that the average numerical value of r is within a range from 1.9 to 2.1,
- (2) 1 to 200 parts by weight of a reinforcing or non-reinforcing filler or mixtures thereof,
- (3) 0.01 to 20 parts by weight of a boric acid-containing additive for the production of the pellet material, and
- (4) optionally further auxiliaries selected from the group of processing aids, plasticizers, pigments, and stabilizers;
- wherein the organopolysiloxane pellets having a particle size of 1 to 100 mm;
- and
- wherein the contents of components (A), (B), and (C) in % by weight are in each case based on the total weight of the compositions.
The composition of claim 10, wherein the vinyl acetate-based homopolymers, copolymers or terpolymers employed are ones selected from the group comprising
- vinyl acetate homopolymers,
- copolymers of vinyl acetate and ethylene,
- copolymers of vinyl acetate and vinyl laurate,
- terpolymers of vinyl acetate, ethylene, and versatic esters,
- terpolymers of vinyl acetate, ethylene, and acrylate,
- terpolymers of vinyl acetate, vinyl laurate, and acrylate, and
- mixtures thereof.
A process for producing compositions, comprising:
- providing components (A), (B) and (C);
- wherein the component (A) is 65% to 99.4% by weight of biopolymers selected from the group consisting of
- polylactic acid (PLA),
- polybutylene succinate (PBS),
- polybutylene succinate adipate (PBSA),
- thermoplastic starch (TPS),
- polyhydroxyalkanoate (PHA),
- polybutylene adipate terephthalate (PBAT),
- polybutylene sebacate terephthalate (PBST),
- polyhydroxybutyrate (PHB),
- polycaprolactone (PCL),
- cellophane (CA), and
- mixtures thereof,
- wherein the component (B) is 0.5 to 30% by weight of homopolymers, copolymers or terpolymers based on vinyl acetate, and
- wherein the component (C) is 0.1% to 5% by weight of organopolysiloxane pellets comprising
- (1) 100 parts by weight of at least one polyorganosiloxane composed of units of general formula
- RrSiO(4-r/2) (I)
- where R is identical or different and is a substituted or unsubstituted hydrocarbon radical and r is 0, 1, 2 or 3, with the proviso that the average numerical value of r is within a range from 1.9 to 2.1,
- (2) 1 to 200 parts by weight of a reinforcing or non-reinforcing filler or mixtures thereof,
- (3) 0.01 to 20 parts by weight of a boric acid-containing additive for the production of the pellet material, and
- (4) optionally further auxiliaries selected from the group of processing aids, plasticizers, pigments, and stabilizers,
- wherein the organopolysiloxane pellets having a particle size of 1 to 100 mm, and
- wherein the contents of components (A), (B), and (C) in % by weight are in
- each case based on the total weight of the compositions;
- and
- mixing the components (A), (B) and (C) together.
Dependencies are inferred from the claim text.