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US 2024/0186499 A1Published application
Titanium-containing oxide powder, negative electrode active material composition using same, and all-solid-state secondary battery
AssigneeUbe Corporation
InventorsKei SHIMAMOTO, Takumi TAKENAKA
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Abstract
Provided is a titanium-containing oxide powder whose main component is a titanium-containing oxide represented by Li4Ti5O12 or Ti1−X/2Nb2O7−X (0≤X<2), the titanium-containing oxide powder containing the titanium-containing oxide particles and a solvate ionic liquid, the solvate ionic liquid comprising a Li salt and an organic solvent.
Claims14
A titanium-containing oxide powder whose main component is a titanium-containing oxide represented by Li4Ti5O12 or Ti1−X/2Nb2O7−X (0≤X<2),
- the titanium-containing oxide powder containing the titanium-containing oxide particles and a solvate ionic liquid,
- the solvate ionic liquid comprising, a Li salt and an organic solvent.
3:
- The titanium-containing oxide powder according to claim 1, wherein the titanium-containing oxide powder has a specific surface area of 1 m2/g or more and 10 m2/g or less.
4:
- The titanium-containing oxide powder according to claim 1, wherein Al is present on particle surfaces of the titanium-containing oxide powder.
5:
- The titanium-containing oxide powder according to claim 1, wherein the Li salt is at least one type of Li salt selected from a group consisting of LiPF6, LiBF4, LiN(SO2F)2, LiN(SO2CF3)2, and LiN(SO2C2F5)2.
6:
- The titanium-containing oxide powder according to claim 1, wherein the Li salt comprises at least two types or more of Li salts selected from a group consisting of LiPF6, LiBF4, LiN(SO2F)2, LiN(SO2CF3)2, and LiN(SO2C2F)2.
7:
- The titanium-containing oxide powder according to claim 1, wherein the Li salt comprises at least one type of Li salt selected from a group consisting of LiPF6, LiBF4, LiN(SO2F)2, LiN(SO2CF)2, and LiN(SO2C2F5)2, and the Li salt further comprises at least one type of Li salt selected from a group consisting of a Li salt having an oxalic acid frame, a Li salt having a phosphoric acid frame, and a Li salt having an S═O group.
8:
- The titanium-containing oxide powder according to claim 1, wherein the organic solvent is an ether compound.
9:
- The titanium-containing oxide powder according to claim 1, wherein a molar ratio of the Li salt to the organic solvent is 0.3 or more and 2.5 or less.
10:
- The titanium-containing oxide powder according to claim 1, wherein a proportion of the solvate ionic liquid to the titanium-containing oxide powder is 0.1 mass % or more and 30 mass % or less.
11:
- A negative electrode active material composition comprising:
- a titanium-containing oxide powder according to claim 1;
- and
- an inorganic solid electrolyte having conductivity for metal ions belonging to Group 1 of Periodic Table.
1 more element
12:
- The negative electrode active material composition according to claim 11, wherein the inorganic solid electrolyte is a sulfide inorganic solid electrolyte.
13:
- The negative electrode active material composition according to claim 11, wherein a content of the inorganic solid electrolyte is 1 mass % or more and 50 mass % or less in the negative electrode active material composition.
14:
- An all-solid-state secondary battery comprising a positive electrode layer, a negative electrode layer, and a solid electrolyte laver, wherein the negative electrode layer is a layer containing the negative electrode active material composition according to claim 11.
- A titanium-containing oxide powder whose main component is a titanium-containing oxide represented by Li4Ti5O12 or Ti1−X/2Nb2O7−X (0≤X<2),
- the titanium-containing oxide powder containing the titanium-containing oxide particles and a solvate ionic liquid,
- the solvate ionic liquid comprising a Li salt and an organic solvent.
1 more element
Dependencies are inferred from the claim text.