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US 2024/0176238 A1Published application
Sulfonium salt, resist composition and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsMasaki Ohashi, Jun Hatakeyama, Tatsuya Yamahira, Yuki Suda
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Abstract
A sulfonium salt of specific structure has a high decomposition efficiency and a high acid diffusion controlling ability upon exposure. A resist composition comprising the sulfonium salt offers a high sensitivity, reduced LWR and improved CDU independent of whether it is of positive or negative tone.
Claims15
A sulfonium salt having the formula (1):
- wherein p, q and r are each independently an integer of 0 to 3, s is 1 or 2, and r+s is from 1 to 3,
- R1 and R2 are each independently halogen, trifluoromethyl, trifluoromethoxy, trifluoromethylthio, nitro, cyano, —C(═O)—R4, —O—C(═O)—R5 or —O—R5,
- R3 is halogen, trifluoromethyl, trifluoromethoxy, trifluoromethylthio, nitro, cyano, —O—C(═O)—R5 or —O—R5,
- R4 is a C1-C10 hydrocarbyl group, C1-C10 hydrocarbyloxy group, or —O—R4A, the hydrocarbyl group and hydrocarbyloxy group may be substituted with fluorine or hydroxy, R4A is an acid labile group,
- R5 is a C1-C10 hydrocarbyl group,
- X1 is a single bond, ether bond, carbonyl group, —N(R)—, sulfide bond or sulfonyl group, R is hydrogen or a C1-C6 saturated hydrocarbyl group,
- Xq− is an anion having the formula (2):
- wherein R6 is a single bond or C1-C4 alkanediyl group,
- R7A and R7B are each independently hydrogen, fluorine, or trifluoromethyl, at least one thereof being fluorine or trifluoromethyl,
- R8 is a single bond or C1-C20 hydrocarbylene group which may contain a heteroatom,
- R9 is a C6-C20 straight or branched hydrocarbyl group which may contain a heteroatom or C3-C20 cyclic hydrocarbyl group which may contain a heteroatom, and
- L1 is an ether bond, ester bond, carbonate bond or urethane bond.
9 more elements
Dependencies are inferred from the claim text.