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US 2024/0132432 A1Published application
Fluorine-containing pillararene
AssigneesKyoto University, Daikin Industries, Ltd.
InventorsTomoki OGOSHI, Katsuto ONISHI, Shuhei YAMAGUCHI, Yuko SHIOTANI, Masaji KOMORI, Hirokazu AOYAMA, Yosuke KISHIKAWA, Akiyoshi YAMAUCHI
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Abstract
Provided is a compound represented by Formula (1A) below wherein the symbols are as defined in the description: Also disclosed are a composition containing at least one of the compound and a formed article of the compound.
Claims37
A compound represented by Formula (1A) below:
- wherein R1a is each independently at each occurrence a hydrogen atom or an organic group, R2a is each independently at each occurrence a hydrogen atom or an organic group, R3a is each independently at each occurrence a hydrogen atom or an organic group, R4a is each independently at each occurrence a hydrogen atom or an organic group, the organic group is —(Op1R11aq1)-Rfa wherein:
- R11a is each independently at each occurrence a C1-10 alkylene group or —CONH—, Rfa is a C1-10 fluoroalkyl group, p1 is an integer of 0 to 2, q1 is an integer of 0 to 3, and in (Op1-R11aq1), occurrence order of O and R11a is not limited, or —(Op3-R11pq3)-Rfpwherein:
- R11p is each independently at each occurrence a C1-10 alkylene group, Rfp is a phenyl group substituted by 1 to 5 fluorine, p3 is an integer of 0 to 2, q3 is an integer of 0 to 3, and in (Op3-R11pq3), occurrence order of O and R11p is not limited, provided that at least one of R1a, R2a, R3a, and R4a is —(Op1-R11aq1)-Rfa or —(Op3-R11pq3)-Rfp, and n1 is an integer of 4 to 20.
A compound represented by Formula (1B) below:
- wherein R1b is each independently at each occurrence a hydrogen atom or an organic group, R2b is each independently at each occurrence a hydrogen atom or an organic group, R3b is each independently at each occurrence a hydrogen atom or an organic group, and R4b is each independently at each occurrence a hydrogen atom or an organic group, the organic group is —Op2-R11bq2)-Rfb wherein:
- R11b is each independently at each occurrence a C1-10 alkylene group, Rfb is a C1-10 fluoroalkyl group, p2 is an integer of 0 to 2, q2 is an integer of 0 to 3, and in (Op2-R11bq2), occurrence order of O and R11b is not limited, or —(Op1-R11aq1)-Rfp wherein:
- R11a is each independently at each occurrence a C1-10 alkylene group, Rfp is a phenyl group substituted by 1 to 5 fluorine, p1 is an integer of 0 to 2, q1 is an integer of 0 to 3, and in (Op1-R11aq1), occurrence order of O and R11a is not limited, provided that at least one of R1b, R2b, R3band R4b is —(Op2-R11bq2)-Rfb or —(Op1-R11aq1)-Rfp, and —(Op2-R11bq2)-Rfb or - (Op1-R11aq1)-Rfp has an SP value of 8.0 or less, and n2 is an integer of 4 to 20.
A compound represented by Formula (1C) below:
- wherein R1c is each independently at each occurrence a hydrogen atom or an organic group, R2c is each independently at each occurrence a hydrogen atom or an organic group, R3c is each independently at each occurrence a hydrogen atom or an organic group, R4c is each independently at each occurrence a hydrogen atom or an organic group, the organic group is each independently —O-R12c, R12c is C17-30 alkyl group, provided that at least one of R1c, R2c, R3c, and R4c is —O-R12c, and n3 is an integer of 4 to 20.
A compound represented by Formula (1D) below:
- wherein R1d is each independently at each occurrence a hydrogen atom or an organic group, R2d is each independently at each occurrence a hydrogen atom or an organic group, R3d is each independently at each occurrence a hydrogen atom or an organic group, and R4d is each independently at each occurrence a hydrogen atom or an organic group, the organic group is each independently —O-R12d, R12d is C17-30 alkyl group, provided that at least one of R1d, R2d, R3d, and R4d is —O-R12d, and R123 has an SP value of 8.2 or more, and n4 is an integer of 4 to 20.
Dependencies are inferred from the claim text.