Improved flocculants
OwnerJ. Zach Hilt, Thomas Dziubla +5inventors
InventorsJ. Zach Hilt, Thomas Dziubla, Angela Gutierrez, Molly E. Frazar, Rishabh Shah, Shuo Tang, Skyler Hornback
Life of this patent
Estimating the term…
Abstract
The present invention provides random multi-component polymers, methods to prepare the random multi-component polymers, methods for removing soluble species or insoluble particles from an aqueous solution, and methods for removing soluble species or insoluble particles from an aqueous solution in the human body
Claims20
A random multi-component polymer or salt thereof, the random multi-component polymer comprising two or more monomer components;
- wherein the random multi-component polymer or salt thereof is water miscible and associates with a soluble species or insoluble particle below a specific temperature and then at or above a specific temperature, converts to a flocculated random multi-component polymer or salt thereof is hydrophobic and easily separated from water.
A random multi-component polymer or a salt thereof, the random multi-component polymer comprising:
- a. from about 50 wt % to about 99.8 wt % of a compound of Formula (I);
- b. from about 0 wt % to about 50 wt % of a compound of Formula (II);
- and
- c. from about 0 wt % to about 50 wt % of a compound of Formula (III);
- wherein
- A and B are independently —CH2— or C(═O);
- X1, X2, and X3 are independently CR13R14, O, NR15, NH, S, substituted aryl, unsubstituted aryl, substituted heteroaryl, or unsubstituted heteroaryl;
- R1, R2, R3, R4, R5, R6, R10, R11, and R12 are independently hydrogen, substituted C1-C10 alkyl, unsubstituted C1-C10 alkyl, substituted C1-C10 alkenyl, unsubstituted C1-C10 alkenyl, substituted C1-C10 alkoxy, unsubstituted C1-C10 alkoxy, substituted C1-C10 alkynyl, or unsubstituted C1-C6 alkynyl;
- and
- R7, R8, and R9 are independently absent or selected from a group consisting of hydrogen, substituted C1-C10 alkyl, unsubstituted C1-C10 alkyl, substituted C4-C8 cycloalkyl, unsubstituted C4-C8 cycloalkyl, substituted C1-C10 alkenyl, unsubstituted C1-C10 alkenyl, substituted C4-C8 cycloalkenyl, unsubstituted C4-C8 cycloalkenyl, substituted C1-C10 alkynyl, unsubstituted C1-C10 alkynyl;
- substituted aryl, unsubstituted aryl, substituted heteroaryl, or unsubstituted heteroaryl.
A process for preparing a random multi-component polymer which imparts a temperature responsiveness, the process comprises contacting the compound of Formula (I) with a compound of Formula (II) and a compound of Formula (III) to form the random multi-component polymer according to the following reaction scheme:
- wherein A and B are independently —CH2— or C(═O);
- X1, X2, and X3 are independently CR13R14, O, NR15, NH, S, substituted aryl, unsubstituted aryl, substituted heteroaryl, or unsubstituted heteroaryl;
- R1, R2, R3, R4, R5, R6, R10, R11, and R12 are independently hydrogen, substituted C1-C10 alkyl, unsubstituted C1-C10 alkyl, substituted C1-C10 alkenyl, unsubstituted C1-C10 alkenyl, substituted C1-C10 alkoxy, unsubstituted C1-C10 alkoxy, substituted C1-C10 alkynyl, or unsubstituted C1-C6 alkynyl;
- and
- R7, R8, or R9 are independently absent or selected from a group consisting of hydrogen, substituted C1-C10 alkyl, unsubstituted C1-C10 alkyl, substituted C4-C8 cycloalkyl, unsubstituted C4-C8 cycloalkyl, substituted C1-C10 alkenyl, unsubstituted C1-C10 alkenyl, substituted C4-C8 cycloalkenyl, unsubstituted C4-C8 cycloalkenyl, substituted C1-C10 alkynyl, unsubstituted C1-C10 alkynyl;
- substituted aryl, unsubstituted aryl, substituted heteroaryl, or unsubstituted heteroaryl.
Dependencies are inferred from the claim text.