Flame retardant phosphonium dicarboxylic acid ionic liquid compound, flame retardant synthetic polymer, fiber and fabric containing the same
AssigneeMaterials Modification, Inc.
InventorsKRISHNASWAMY KASTHURI RANGAN, TIRUMALAI SRINIVAS SUDARSHAN
Life of this patent
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Abstract
A phosphorus-containing ionic liquid, a phosphorus-containing a flame retardant additive, and a preparation method thereof are provided. Also provided are co-monomer salt compositions for flame retardant polymers. Also provided are polymers that comprise the phosphorus-containing flame retardant ionic liquid or flame retardant co-monomer salt. The resin composition may be used to make various articles, including fibers, fabrics, and yarns.
Claims7
A flame retardant ionic liquid compound represented by the structure of Formula 1:
- wherein
- X is a chemical moiety comprising a dicarboxylic acid group selected from the group consisting of oxalic acid (ethanedioic acid), malonic acid (propanedioic acid), succinic acid (butanedioic acid), glutaric acid (pentanedioic acid), adipic acid (hexanedioic acid), pimelic acid (heptanedioic acid), suberic acid (octanedioic acid), azelaic acid (nonanedioic acid), sebacic acid (decanedioic acid), undecanedioic acid, dodecanedioic acid, brassylic acid (tridecanedioic acid), thapsic acid (hexadecanedioic acid), heneicosanedioic acid, docosanedioic acid, triacontanedioic acid, and combinations thereof;
- R1 is selected from the group consisting of an alkyl group, an aryl group and combinations thereof;
- R2 is selected from the group consisting of an alkyl group, an aryl group and combinations thereof;
- R3 is selected from the group consisting an alkyl group, an aryl group and combinations thereof;
- A- is an anion selected from the group consisting of bromide, chloride, iodide, adipate, and succinate, oxalate, malonate, glutarate, pimelicate, subericate (octanedioic carboxylic anion), and combinations thereof;
- wherein the alkyl group is CnH2n+1;
- and wherein n = 1 to 20.
A flame retardant intermediate compound represented by structure of Formula 2:
- wherein
- X is a chemical moiety comprising a dicarboxylic acid group selected from the group consisting of oxalic acid (ethanedioic acid), malonic acid (propanedioic acid), succinic acid (butanedioic acid), glutaric acid (pentanedioic acid), adipic acid (hexanedioic acid), pimelic acid (heptanedioic acid), suberic acid (octanedioic acid), azelaic acid (nonanedioic acid), sebacic acid (decanedioic acid), undecanedioic acid, dodecanedioic acid, brassylic acid (tridecanedioic acid), thapsic acid (hexadecanedioic acid), heneicosanedioic acid, docosanedioic acid, triacontanedioic acid, and combinations thereof;
- R1 is selected from the group consisting of an alkyl group, an aryl group and combinations thereof;
- R2 is selected from the group consisting of an alkyl group, an aryl group and combinations thereof;
- R3 is selected from the group consisting an alkyl group, an aryl group and combinations thereof;
- A- is an anion selected from the group consisting of bromide, chloride, iodide, adipate, and succinate, oxalate, malonate, glutarate, pimelicate, subericate (octanedioic carboxylic anion), and combinations thereof;
- wherein the alkyl group is CnH2n+1;
- and wherein n = 1 to 20.
Dependencies are inferred from the claim text.