Composition, film, display device and article prepared therefrom, and method of preparing article

A material comprising a ring-opening reaction product of a compound represented by Formula 2 or Formula 3,

• a compound comprising a ring-opening reaction product of the compound represented by Formula 2 or Formula 3 and a fluorine-containing (poly)ether group represented by Formula 1, or
• a polycondensation product of a ring-opening reaction product of the compound represented by Formula 2 or Formula 3, a compound represented by Formula 1, or a combination thereof:
• wherein, in Formulas 1 to 3,
• Rf is a fluorine-containing (poly)ether group,
• L1 is a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C1 to C20 oxyalkylene group, or a combination thereof,
• Q1 is —C(═O)O—R1, —C(═O)—O—C(═O)—R2, —O—(C═O)—CR3═CR4R5, —O—(C═O)—CR6═CR7—(C═O)—O—R8, —O—C(═O)—O—R9, an epoxy-containing group, or a cyclic carbonate-containing group,
• p1 is an integer of 1 to 10,
• q1, q2, and q3 are each independently an integer of 1 to 10,
• A1, A2, and A3 are each independently ═N—Ru or —S—,
• R1, R2, R5, R8, and R9 are each independently a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• R3, R4, R6, and R7 are each independently a hydrogen, a halogen atom, a hydroxy group, a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• Ra, Rb, Ri, and Rj are each independently a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, a halogen, or a hydroxy group, and
• Rc, Rd, Re, Rf, Rg, Rh, Rk, Rl, Rm, Rn, Ro, Rp, Rq, Rr, Rs, Rt, and Ru are each independently a hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C20 alkenyl group.

An electronic device comprising

• a ring-opening reaction product of a compound represented by Formula 2 or Formula 3,
• a compound comprising a ring-opening reaction product of a compound represented by Formula 2 or Formula 3, a fluorine-containing (poly)ether group represented by Formula 1, or a combination thereof, or
• a polycondensation product of a ring-opening reaction product of a compound represented by Formula 2 or Formula 3, a compound having a fluorine-containing (poly)ether group represented by Formula 1, or a combination thereof:
• wherein, in Formulas 1 to 3,
• Rf is a fluorine-containing (poly)ether group,
• L1 is a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C1 to C20 oxyalkylene group, or a combination thereof,
• Q1 is —C(═O)O—R1, —C(═O)—O—C(═O)—R2, —O—(C═O)—CR3═CR4R5, —O—(C═O)—CR6═CR7—(C═O)—O—R8, —O—C(═O)—O—R9, an epoxy-containing group, or a cyclic carbonate-containing group,
• p1 is an integer of 1 to 10,
• q1, q2, and q3 are each independently an integer of 1 to 10,
• A1, A2, and A3 are each independently ═N—Ru or —S—,
• R1, R2, R5, R8, and R9 are each independently a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• R3, R4, R6, and R7 are each independently a hydrogen, a halogen atom, a hydroxy group, a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• Ra, Rb, Ri, and Rj are each independently a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, a halogen, or a hydroxy group, and
• Rc, Rd, Re, Rf, Rg, Rh, Rk, Rl, Rm, Rn, Ro, Rp, Rq, Rr, Rs, Rt, and Ru are each independently a hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C20 alkenyl group.

An article comprising:

• a substrate;
• and
• a material disposed on the substrate, wherein
• the material comprises
• a ring-opening reaction product of a compound represented by Formula 2 or Formula 3,
• a compound comprising a ring-opening reaction product of a compound represented by Formula 2 or Formula 3, a fluorine-containing (poly)ether group represented by Formula 1, or a combination thereof, or
• a polycondensation product of a ring-opening reaction product of a compound represented by Formula 2 or Formula 3, a compound having a fluorine-containing (poly)ether group represented by Formula 1, or a combination thereof:
• wherein, in Formulas 1 to 3,
• Rf is a fluorine-containing (poly)ether group,
• L1 is a substituted or unsubstituted C1 to C20 alkylene group, a substituted or unsubstituted C1 to C20 oxyalkylene group, or a combination thereof,
• Q1 is —C(═O)O—R1, —C(═O)—O—C(═O)—R2, —O—(C═O)—CR3═CR4R5, —O—(C═O)—CR6═CR7—(C═O)—O—R8, —O—C(═O)—O—R9, an epoxy-containing group, or a cyclic carbonate-containing group,
• p1 is an integer of 1 to 10,
• q1, q2, and q3 are each independently an integer of 1 to 10,
• A1, A2, and A3 are each independently ═N—Ru or —S—,
• R1, R2, R5, R8, and R9 are each independently a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• R3, R4, R6, and R7 are each independently a hydrogen, a halogen atom, a hydroxy group, a substituted or unsubstituted C1 to C20 alkyl group, or a substituted or unsubstituted C6 to C20 aryl group,
• Ra, Rb, Ri, and Rj are each independently a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, a halogen, or a hydroxy group, and
• Rc, Rd, Re, Rf, Rg, Rh, Rk, Rl, Rm, Rn, Ro, Rp, Rq, Rr, Rs, Rt, and Ru are each independently a hydrogen, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C20 alkenyl group.