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US 2023/0127105 A1Published application
Nonaqueous Electrolytic Solution and Nonaqueous Electrolytic Solution Battery
AssigneesMitsubishi Chemical Corporation, Mu Ionic Solutions Corporation
InventorsEiji Nakazawa, Kaho Tamai
Life of this patent
Estimating the term…
Abstract
Provided are: a nonaqueous electrolytic solution for a nonaqueous electrolytic solution battery including a positive electrode and a negative electrode that are capable of occluding and releasing metal ions, which nonaqueous electrolytic solution is characterized by containing a compound represented by Formula (1) along with an alkali metal salt and a nonaqueous solvent.
Claims11
A nonaqueous electrolytic solution for a nonaqueous electrolytic solution battery comprising a positive electrode and a negative electrode that are capable of occluding and releasing metal ions,
- wherein the nonaqueous electrolytic solution comprises a compound represented by the following Formula (1) along with an alkali metal salt and a nonaqueous solvent:
- wherein, R1 represents a hydrogen atom, a halogen atom, or a monovalent hydrocarbon group optionally having a substituent;
- R2 represents a hydrogen atom, a monovalent hydrocarbon group optionally having a substituent, or an alkoxy group optionally having a substituent;
- X1 represents a divalent hydrocarbon group optionally having a substituent;
- n1 represents 2 or 3;
- p1 represents an integer of 0 to 2, q1 represents an integer of 1 to 3, and p1+q1=2 or 3;
- two of R1(s) and X1(s) are optionally bound to each other to form a ring;
- and A1 represents a divalent or trivalent atomic group represented by the following Formula (2-1), or a trivalent atomic group represented by the following Formula (3-1):
- wherein, Z1 represents a carbon atom, a sulfur atom, a phosphorus atom, or a boron atom;
- Y101 represents an oxygen atom or a sulfur atom;
- Y1, Y2, and Y3 each independently represent a single bond, an oxygen atom, a sulfur atom, or an NR101 group;
- R101 represents a hydrogen atom or a monovalent hydrocarbon group;
- when R101 is a monovalent hydrocarbon group, this R101 is optionally bound to one of R1 and X1 in Formula (1) to form a ring;
- r1 is 1 when Z1 is a carbon atom;
- 0, 1, or 2 when Z1 is a sulfur atom;
- 0 or 1 when Z1 is a phosphorus atom;
- or 0 when Z1 is a boron atom;
- r2 is 0 when Z1 is a carbon atom or a sulfur atom, or 1 when Z1 is a phosphorus atom or a boron atom;
- and
- * represents a binding site with R1 or X1 in Formula (1),
- with a proviso that, when Z1 is a sulfur atom and r1 is 2, Y1 and Y2 are not single bonds simultaneously:
- wherein, Y4, Y5, and Y6 each independently represent an oxygen atom, a sulfur atom, or NR201;
- R201 represents a hydrogen atom or a monovalent hydrocarbon group;
- and * represents a binding site with R1 or X1 in Formula (1)
21 more elements
A nonaqueous electrolytic solution battery, comprising:
- a positive electrode and a negative electrode that are capable of occluding and releasing metal ions;
- and
- a nonaqueous electrolytic solution,
- wherein
- a negative electrode active material contained in the negative electrode comprises a material comprising a Li-alloyable metal element and/or metalloid element, and
- the nonaqueous electrolytic solution comprises an alkali metal salt, a nonaqueous solvent, and a compound represented by the following Formula (4):
- wherein, R3 represents a hydrogen atom, a halogen atom, or a monovalent hydrocarbon group optionally having a substituent;
- R4 represents a hydrogen atom, a monovalent hydrocarbon group optionally having a substituent, or an alkoxy group optionally having a substituent;
- X2 represents a divalent hydrocarbon group optionally having a substituent;
- n2 represents an integer of 1 to 3;
- p2 represents an integer of 0 to 2, q2 represents an integer of 1 to 3, and p2+q2=2 or 3;
- two of R3(s) and X2(s) are optionally bound to each other to form a ring;
- and A2 represents a divalent or trivalent atomic group represented by the following Formula (5-1), or a trivalent atomic group represented by the following Formula (6-1):
- wherein, Z3 represents a carbon atom, a sulfur atom, a phosphorus atom, or a boron atom;
- Y102 represents an oxygen atom or a sulfur atom;
- Y10, Y11, and Y12 each independently represent a single bond, an oxygen atom, a sulfur atom, or NR102;
- R102 represents a hydrogen atom or a monovalent hydrocarbon group;
- r6 is 1 when Z3 is a carbon atom;
- 0, 1, or 2 when Z3 is a sulfur atom;
- 0 or 1 when Z3 is a phosphorus atom;
- or 0 when Z3 is a boron atom;
- r6 is 0 when Z3 is a carbon atom or a sulfur atom, or 1 when Z3 is a phosphorus atom or a boron atom;
- and
- * represents a binding site with R3 or X2 in Formula (4),
- with a proviso that, when Z3 is a sulfur atom and r6 is 2, Y10 and Y11 are not single bonds simultaneously:
- wherein, Y13, Y14, and Y15 each independently represent an oxygen atom, a sulfur atom, or NR202;
- R202 represents a hydrogen atom or a monovalent hydrocarbon group;
- and * represents a binding site with R3 or X2 in Formula (4).
25 more elements
Dependencies are inferred from the claim text.