Novel materials with extremely durable intercalation of lithium and manufacturing methods thereof

A composite particle, comprising:

• (i) a porous carbon framework comprising micropores and mesopores, the porous carbon framework further comprising a total pore volume of greater than 0.5 cm3/g;
• a volume fraction of macropores in the range from 0-10%;
• and a fractional pore volume of pores at or below 10 nm that comprises at least 75% of the total pore volume;
• (ii) a first electrochemical modifier consisting of silicon and comprising 10 to 80% of the composite particle by weight;
• and
• (iii) a second electrochemical modifier,
• and wherein a plurality of the composite particles further comprises a Dv0 ranging from 1 nm to 5 um;
• a Dv50 ranging from 5 nm to 20 um;
• and a Dv100 ranging from 8 nm to 100 um.