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US 2023/0056794 A1Published application
Polyethylene Powder and Molded Article Thereof
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsKazuya Shikata, Haruka Yokoyama
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Abstract
A polyethylene powder satisfying (Requirements 1 to 3): (Requirement 1): viscosity-average molecular weight (Mv) is 200,000 or more and 3,000,000 or less (Requirement 2): complex viscosity |η*|m obtained by measurement under predetermined <Conditions for Measurement of Slurry Viscoelasticity>satisfies the following formula (1): 590.0×(Mv×10−4)1.18≥|η*|m≥13.3×(Mv×10−4)1.18 (1) (Requirement 3): a value of any peak when d(log|η*|)/dT is plotted against temperature is 1.0 or more and 3.0 or less.
Claims20
A polyethylene powder satisfying the following (Requirements 1 to 3):
- (Requirement 1):
- viscosity-average molecular weight (Mv) is 200,000 or more and 3,000,000 or less
- (Requirement 2):
- complex viscosity |η*|m obtained by measurement under the following <Conditions for Measurement of Slurry Viscoelasticity>satisfies the following formula (1):
- 590.0×(Mv×104)1.18≥|η*|m≥13.3×(Mv×10−4)1.18 (1)
- <Conditions for Measurement of Slurry Viscoelasticity>
- measuring apparatus:
- MARS Ill manufactured by Thermo Fisher Scientific K.K.
- stage:
- 20 mm ϕ
- plate:
- 20 mm ϕ parallel plate
- gap:
- 0.5 mm
- slurry composition:
- 30 parts by mass of a polyethylene powder, 70 parts by mass of a liquid paraffin
- (the polyethylene powder:
- a powder passing through a sieve having an opening of 425 μm in accordance with JIS Z 8801 standard is used for measurement)
- measurement conditions:
- complex viscosity |η*| is measured by the following steps 1 to 2:
- step 1 a slurry is kept at 100° C. for 2 min
- step 2 after the step 1, temperature is increased from 100° C. to 140° C. at 1° C./min, and viscoelasticity during the temperature increase is measured at a frequency of 1 Hz and a strain of 10% under a nitrogen atmosphere
- determination of |η*|m:
- a temperature at a point in time when a value of d(log|η*|)/dT associated with dissolution of the polyethylene powder first reaches 0.03 or less after passing a peak is regarded as a temperature at which the dissolution of the polyethylene powder is completed, and complex viscosity |η*| at the temperature is |η*|m
- (T is measurement temperature)
- (Requirement 3):
- a value of any peak when d(log |η*|)/dT is plotted against temperature is 1.0 or more and 3.0 or less.
24 more elements
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