Polyamide compositions
AssigneeLANXESS Deutschland GmbH
InventorsJochen ENDTNER, Matthias BIENMUELLER, Fabio PASSERI
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Abstract
Flame resistant compositions based on nylon-6 (PA 6) or nylon-6,6 (PA 66) may include melamine cyanurate, glass fibres and non-fibrous and non-foamed ground glass having a specific particle size distribution, geometry and optionally sizing. Methods for producing the composition are also provided, as well as use of the compositions for production of products for the electrical industry, preferably electrical components such as residual current circuit breakers and other circuit breakers.
Claims20
A circuit breaker comprising a flame-retardant polyamide composition comprising:
- A) 5% to 92.9% by weight of nylon-6, nylon-6,6, or copolyamides based on nylon 6 and/or nylon 6,6,
- B) 5% to 80% by weight of non-fibrous and non-foamed ground glass having a d90 of 5 to 250 μm, and a length of 0.01 to 0.5 mm,
- C) 4% to 6% by weight of chopped long glass fibres having an original length of 1 to 50 mm, and
- D) 0.1% to 40% by weight of the melamine cyanurate,
- with the proviso that the sum total of all the percentages by weight is always 100%
An article of manufacture for an electronic circuit, the article comprising a flame-retardant polyamide composition comprising:
- A) 30% to 80% by weight of nylon-6 or nylon 6,6, wherein the nylon-6 or the nylon-6,6 has a viscosity number of 80 to 180 ml/g, determined in a 0.5% by weight solution in 96% by weight sulphuric acid at 25° C. to ISO 307,
- B) 15% to 50% by weight of non-fibrous and non-foamed ground glass obtained by grinding glass with a mill, wherein the ground glass has a length of 0.01 to 0.5 mm, a d90 of 5 to 250 μm, a d10 of 0.3 to 10 μm, and a d50 of 3 to 50 μm,
- C) 4% to 6% by weight of chopped long glass fibres having an original length of 1 to 50 mm,
- D) 1% to 20% by weight of melamine cyanurate,
- G) 0.01% to 60% by weight of ehtylenebisstearylamide, and
- K) 0.01% to 20% by weight of 3,3′-bis(3,5-di-tert-butyl-4-hydroxyphenyl)-N,N′-hexamethylenedipropionamide.
- with the proviso that the sum total of all the percentages by weight is 100%.
A circuit breaker component comprising a flame-retardant polyamide composition comprising:
- A) 5% to 92.9% by weight of nylon-6, nylon-6,6 or copolyamides based on nylon 6 and/or nylon 66;
- B) 5% to <42% by weight of non-fibrous and non-foamed ground glass of irregular shapes with broken edges and having a d90 of 5 to 250 μm, a length of 0.01 to 0.5 mm, and an aspect ratio of length to diameter (L/D ratio) of less than 5;
- C) 4% to 6% by weight of chopped long glass fibres having a fibre diameter of 7 to 18 μm, and an original length of 1 to 50 mm;
- and
- D) 0.1% to 40% by weight of melamine cyanurate.
Dependencies are inferred from the claim text.